%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  0.82485254   -2.47929443   -0.54308079
 H                  1.28398071   -1.79254636   -1.26155965
 H                 -0.07403124   -0.75705437    0.62421324
 O                 -0.89122446    0.12721316    0.50052265
 C                 -2.14908053   -0.03039393   -0.29062347
 H                 -2.81588903    0.78099089    0.01852279
 O                  0.65286412   -1.71204591    0.72882978
 H                 -2.55287274   -0.98178327   -0.01365746
 H                 -1.89415198    0.05403434   -1.32637600
 H                 -0.16122992   -2.75444243   -0.85426400
 H                  1.46841205   -3.30912345   -0.33786145
 H                 -0.46330655    0.96073337    0.29140466
 O                  0.06384658    2.00532666    0.00458624
 C                  1.55111438    1.91409000   -0.12078180
 H                 -0.32708410    2.38031402   -0.80756487
 H                  1.75259298    1.20891334   -0.93365677
 H                  1.90034329    1.52882220    0.81436945
 H                  1.91802826    2.89078055   -0.35816292

C H O 0
6-31G*
****








