%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  0.83411864   -2.63905845   -0.37689952
 H                  1.66442149   -2.03778860   -0.76122388
 H                 -0.34302074   -0.78017391    0.16676342
 O                 -0.88484573    0.16677326   -0.35740250
 C                 -2.24342660    0.47185987    0.18493894
 H                 -2.10611275    0.74126445    1.23713493
 O                  0.12371496   -1.79025723    0.62852074
 H                 -2.80608178   -0.43369032    0.09384558
 H                 -2.63957993    1.29344688   -0.37448696
 H                  0.11932364   -2.83986123   -1.14738402
 H                  1.19190531   -3.51153476    0.12874245
 H                 -0.32393993    0.94495349   -0.31971670
 O                  0.38375064    1.91965916   -0.29842641
 C                  1.70951343    1.68633621    0.35266514
 H                  0.50135510    2.28332424   -1.19672960
 H                  2.21892449    0.92191134   -0.24297608
 H                  1.49276154    1.32304607    1.33548704
 H                  2.24785181    2.61087500    0.33478188

C H O 0
6-31G*
****






