%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 H                  0.25826094   -0.00371751    0.01233212
 O                  0.20713208    1.05422142   -0.57348718
 C                 -0.28374951    2.19263358    0.26078321
 H                  0.44386854    2.32433896    1.06810965
 H                 -1.23202210    1.88457291    0.64908427
 H                 -0.32585080    3.05952602   -0.36501626

C H O 0
6-31G*
****






