%nproc=24
%mem=2GB
%chk=tx_mecn_FREQ.chk
#p freq b3lyp/gen pseudo=read EmpiricalDispersion=GD3BJ scrf=(pcm,solvent=acetonitrile) pop=(orbitals=20) optcyc=300 nosymm

Title Card Required

0 1
 C    -9.145633    -0.385275     0.008134
 C    -7.758984    -0.465278     0.019796
 C    -6.982301     0.709610     0.014714
 C    -7.607773     1.973264    -0.002324
 C    -9.018251     2.023296    -0.013938
 C    -9.783533     0.867138    -0.008853
 C    -6.878580     3.265142    -0.008872
 C    -5.395223     3.274019     0.003195
 C    -4.595401     2.112830     0.020552
 C    -3.191139     2.219866     0.030762
 H    -2.581305     1.314308     0.044068
 C    -2.586412     3.470318     0.023894
 C    -3.370333     4.636923     0.006716
 C    -4.752730     4.530720    -0.003392
 H    -9.736353    -1.303445     0.012267
 H    -7.264605    -1.438653     0.032951
 H    -9.481650     3.009815    -0.027053
 H   -10.873013     0.928451    -0.017961
 H    -1.496854     3.539682     0.031924
 H    -2.894011     5.618708     0.001390
 H    -5.389006     5.415634    -0.016801
 S    -5.235909     0.470599     0.030967
 O    -7.504329     4.329452    -0.024566

H     0
S    4   1.00
      1.301000D+01           1.968500D-02
      1.962000D+00           1.379770D-01
      4.446000D-01           4.781480D-01
      1.220000D-01           5.012400D-01
S    1   1.00
      1.220000D-01           1.000000D+00
P    1   1.00
      7.270000D-01           1.0000000
****
C     0
S    9   1.00
      6.665000D+03           6.920000D-04
      1.000000D+03           5.329000D-03
      2.280000D+02           2.707700D-02
      6.471000D+01           1.017180D-01
      2.106000D+01           2.747400D-01
      7.495000D+00           4.485640D-01
      2.797000D+00           2.850740D-01
      5.215000D-01           1.520400D-02
      1.596000D-01          -3.191000D-03
S    9   1.00
      6.665000D+03          -1.460000D-04
      1.000000D+03          -1.154000D-03
      2.280000D+02          -5.725000D-03
      6.471000D+01          -2.331200D-02
      2.106000D+01          -6.395500D-02
      7.495000D+00          -1.499810D-01
      2.797000D+00          -1.272620D-01
      5.215000D-01           5.445290D-01
      1.596000D-01           5.804960D-01
S    1   1.00
      1.596000D-01           1.000000D+00
P    4   1.00
      9.439000D+00           3.810900D-02
      2.002000D+00           2.094800D-01
      5.456000D-01           5.085570D-01
      1.517000D-01           4.688420D-01
P    1   1.00
      1.517000D-01           1.000000D+00
D    1   1.00
      5.500000D-01           1.0000000
****
O     0
S    9   1.00
      1.172000D+04           7.100000D-04
      1.759000D+03           5.470000D-03
      4.008000D+02           2.783700D-02
      1.137000D+02           1.048000D-01
      3.703000D+01           2.830620D-01
      1.327000D+01           4.487190D-01
      5.025000D+00           2.709520D-01
      1.013000D+00           1.545800D-02
      3.023000D-01          -2.585000D-03
S    9   1.00
      1.172000D+04          -1.600000D-04
      1.759000D+03          -1.263000D-03
      4.008000D+02          -6.267000D-03
      1.137000D+02          -2.571600D-02
      3.703000D+01          -7.092400D-02
      1.327000D+01          -1.654110D-01
      5.025000D+00          -1.169550D-01
      1.013000D+00           5.573680D-01
      3.023000D-01           5.727590D-01
S    1   1.00
      3.023000D-01           1.000000D+00
P    4   1.00
      1.770000D+01           4.301800D-02
      3.854000D+00           2.289130D-01
      1.046000D+00           5.087280D-01
      2.753000D-01           4.605310D-01
P    1   1.00
      2.753000D-01           1.000000D+00
D    1   1.00
      1.185000D+00           1.0000000
****
S     0
S    12   1.00
      1.108000D+05           2.476350D-04
      1.661000D+04           1.920260D-03
      3.781000D+03           9.961920D-03
      1.071000D+03           4.029750D-02
      3.498000D+02           1.286040D-01
      1.263000D+02           3.034800D-01
      4.926000D+01           4.214320D-01
      2.016000D+01           2.307810D-01
      5.720000D+00           1.789710D-02
      2.182000D+00          -2.975160D-03
      4.327000D-01           8.495220D-04
      1.570000D-01          -3.679360D-04
S    12   1.00
      1.108000D+05          -6.870390D-05
      1.661000D+04          -5.276810D-04
      3.781000D+03          -2.796710D-03
      1.071000D+03          -1.126510D-02
      3.498000D+02          -3.888340D-02
      1.263000D+02          -9.950250D-02
      4.926000D+01          -1.997400D-01
      2.016000D+01          -1.233600D-01
      5.720000D+00           5.131940D-01
      2.182000D+00           6.071200D-01
      4.327000D-01           3.967530D-02
      1.570000D-01          -9.468640D-03
S    12   1.00
      1.108000D+05           1.990770D-05
      1.661000D+04           1.534830D-04
      3.781000D+03           8.095030D-04
      1.071000D+03           3.289740D-03
      3.498000D+02           1.129670D-02
      1.263000D+02           2.963850D-02
      4.926000D+01           5.998510D-02
      2.016000D+01           4.132480D-02
      5.720000D+00          -2.074740D-01
      2.182000D+00          -3.928890D-01
      4.327000D-01           6.328400D-01
      1.570000D-01           5.569240D-01
S    1   1.00
      1.570000D-01           1.000000D+00
P    8   1.00
      3.997000D+02           4.475410D-03
      9.419000D+01           3.417080D-02
      2.975000D+01           1.442500D-01
      1.077000D+01           3.539280D-01
      4.119000D+00           4.590850D-01
      1.625000D+00           2.063830D-01
      4.726000D-01           1.021410D-02
      1.407000D-01          -6.031220D-05
P    8   1.00
      3.997000D+02          -1.162510D-03
      9.419000D+01          -8.656640D-03
      2.975000D+01          -3.908860D-02
      1.077000D+01          -9.346250D-02
      4.119000D+00          -1.479940D-01
      1.625000D+00           3.019040D-02
      4.726000D-01           5.615730D-01
      1.407000D-01           5.347760D-01
P    1   1.00
      1.407000D-01           1.000000D+00
D    1   1.00
      4.790000D-01           1.0000000
****





