%nproc=24
%mem=2GB
%chk=subs3-e_M3.chk
#p opt freq geom=checkpoint guess=read b3lyp/gen pseudo=read EmpiricalDispersion=GD3BJ scrf=(pcm,solvent=acetonitrile) pop=(orbitals=20) optcyc=300 nosymm

Title Card Required

0 3

H     0
S    4   1.00
      1.301000D+01           1.968500D-02
      1.962000D+00           1.379770D-01
      4.446000D-01           4.781480D-01
      1.220000D-01           5.012400D-01
S    1   1.00
      1.220000D-01           1.000000D+00
P    1   1.00
      7.270000D-01           1.0000000
****
B     0
S    9   1.00
      4.570000D+03           6.960000D-04
      6.859000D+02           5.353000D-03
      1.565000D+02           2.713400D-02
      4.447000D+01           1.013800D-01
      1.448000D+01           2.720550D-01
      5.131000D+00           4.484030D-01
      1.898000D+00           2.901230D-01
      3.329000D-01           1.432200D-02
      1.043000D-01          -3.486000D-03
S    9   1.00
      4.570000D+03          -1.390000D-04
      6.859000D+02          -1.097000D-03
      1.565000D+02          -5.444000D-03
      4.447000D+01          -2.191600D-02
      1.448000D+01          -5.975100D-02
      5.131000D+00          -1.387320D-01
      1.898000D+00          -1.314820D-01
      3.329000D-01           5.395260D-01
      1.043000D-01           5.807740D-01
S    1   1.00
      1.043000D-01           1.000000D+00
P    4   1.00
      6.001000D+00           3.548100D-02
      1.241000D+00           1.980720D-01
      3.364000D-01           5.052300D-01
      9.538000D-02           4.794990D-01
P    1   1.00
      9.538000D-02           1.000000D+00
D    1   1.00
      3.430000D-01           1.0000000
****
C     0
S    9   1.00
      6.665000D+03           6.920000D-04
      1.000000D+03           5.329000D-03
      2.280000D+02           2.707700D-02
      6.471000D+01           1.017180D-01
      2.106000D+01           2.747400D-01
      7.495000D+00           4.485640D-01
      2.797000D+00           2.850740D-01
      5.215000D-01           1.520400D-02
      1.596000D-01          -3.191000D-03
S    9   1.00
      6.665000D+03          -1.460000D-04
      1.000000D+03          -1.154000D-03
      2.280000D+02          -5.725000D-03
      6.471000D+01          -2.331200D-02
      2.106000D+01          -6.395500D-02
      7.495000D+00          -1.499810D-01
      2.797000D+00          -1.272620D-01
      5.215000D-01           5.445290D-01
      1.596000D-01           5.804960D-01
S    1   1.00
      1.596000D-01           1.000000D+00
P    4   1.00
      9.439000D+00           3.810900D-02
      2.002000D+00           2.094800D-01
      5.456000D-01           5.085570D-01
      1.517000D-01           4.688420D-01
P    1   1.00
      1.517000D-01           1.000000D+00
D    1   1.00
      5.500000D-01           1.0000000
****
O     0
S    9   1.00
      1.172000D+04           7.100000D-04
      1.759000D+03           5.470000D-03
      4.008000D+02           2.783700D-02
      1.137000D+02           1.048000D-01
      3.703000D+01           2.830620D-01
      1.327000D+01           4.487190D-01
      5.025000D+00           2.709520D-01
      1.013000D+00           1.545800D-02
      3.023000D-01          -2.585000D-03
S    9   1.00
      1.172000D+04          -1.600000D-04
      1.759000D+03          -1.263000D-03
      4.008000D+02          -6.267000D-03
      1.137000D+02          -2.571600D-02
      3.703000D+01          -7.092400D-02
      1.327000D+01          -1.654110D-01
      5.025000D+00          -1.169550D-01
      1.013000D+00           5.573680D-01
      3.023000D-01           5.727590D-01
S    1   1.00
      3.023000D-01           1.000000D+00
P    4   1.00
      1.770000D+01           4.301800D-02
      3.854000D+00           2.289130D-01
      1.046000D+00           5.087280D-01
      2.753000D-01           4.605310D-01
P    1   1.00
      2.753000D-01           1.000000D+00
D    1   1.00
      1.185000D+00           1.0000000
****







