%chk=Carbonate-Alt.chk
%nprocshared=8
%mem=20GB
#p opt=(noeigentest) iop(1/8=10) freq=noraman wb97xd/6-311G** nosymm scrf=(smd,solvent=butanone)

Dimer

0 1
 Al                 2.94832800   10.70875700    1.79448400
 N                  1.95442300   11.87160700    0.41323000
 O                  4.58374400   10.93151200    1.17383700
 O                  2.24704500    9.17368900    1.22556500
 O                  3.01747900   12.57981000    2.75065100
 C                  2.90098200   12.89539900   -0.14325800
 H                  3.16172100   13.58030800    0.66471500
 H                  2.35576700   13.47357700   -0.89919100
 C                  4.15217400   12.30769300   -0.74900300
 C                  4.93214000   11.37659700   -0.04190800
 C                  6.12495100   10.89089400   -0.61477900
 C                  6.50575200   11.34647100   -1.87251700
 H                  7.42799900   10.96454700   -2.30834100
 C                  5.74089100   12.26688300   -2.59823700
 C                  4.56332300   12.72780800   -2.01747500
 H                  3.94236900   13.43914800   -2.55951300
 C                  1.51187800   11.01060200   -0.73415900
 H                  2.42438000   10.61771700   -1.19266500
 H                  1.02369300   11.65874200   -1.47172600
 C                  0.61673100    9.87071600   -0.35316700
 C                  1.08945400    8.95579400    0.59560500
 C                  0.34973700    7.79226200    0.87471000
 C                 -0.86986600    7.60836800    0.22724900
 H                 -1.45087800    6.71608800    0.45735900
 C                 -1.37991500    8.53111700   -0.69392700
 C                 -0.61378400    9.66103700   -0.97464800
 H                 -0.97236800   10.39252900   -1.69704400
 C                  0.74389800   12.53786100    0.96917200
 H                  0.07924100   11.75128300    1.34577800
 H                  0.22343800   13.03702100    0.14171800
 C                  0.95713200   13.54251400    2.07697600
 C                  2.01524000   13.51197800    2.97639300
 C                  2.11178600   14.38011300    4.06551900
 C                  1.09128600   15.31190300    4.23616600
 H                  1.14832200   15.99745700    5.07860700
 C                  0.00797700   15.39075100    3.35706700
 C                 -0.03621300   14.50219800    2.28572200
 H                 -0.87098100   14.54355600    1.58944200
 O                 -1.48414000   10.91089200    2.69848200
 C                 -1.39601100    9.58106900    3.22582300
 C                 -1.21624800   10.74423700    4.08688200
 H                 -2.33498600    9.03073000    3.24726300
 H                 -0.52181400    9.02268500    2.90739400
 C                  0.87695000    6.80931000    1.88355800
 H                  1.81500300    6.35395600    1.54436500
 H                  1.09799700    7.30229700    2.83820500
 H                  0.15468800    6.00751700    2.06629400
 C                  3.26767000   14.27944500    5.02648400
 H                  3.30745500   13.29427200    5.51102500
 H                  4.23250500   14.45332400    4.53246500
 H                  3.17116100   15.02561600    5.81878600
 C                 -1.09066100   16.39897200    3.57733500
 H                 -1.81608600   16.03397200    4.31482400
 H                 -0.69099600   17.34608400    3.95418300
 H                 -1.63579500   16.60087800    2.65025800
 C                 -2.70683400    8.29238600   -1.37117200
 H                 -2.63335200    7.51072000   -2.13791600
 H                 -3.46859200    7.96797600   -0.65327900
 H                 -3.07197100    9.20068300   -1.86134300
 C                  6.95077200    9.89323100    0.14994100
 H                  7.29198900   10.30739200    1.10604000
 H                  6.36891000    8.99521100    0.38778800
 H                  7.83189000    9.59059400   -0.42451000
 C                  6.18318200   12.73124700   -3.96383800
 H                  7.17320800   13.20094300   -3.92533800
 H                  6.25028500   11.89525100   -4.67059800
 H                  5.48294100   13.46297200   -4.37953200
 H                 -2.03398900   11.04665600    4.74184700
 C                  0.12665100   11.18023500    4.59949000
 H                  0.17466300   12.27349100    4.64146200
 H                  0.27683700   10.78193800    5.60531500
 O                  1.18569200   10.72460400    3.75573600
 C                  2.31437300   10.21994100    4.36988000
 O                  2.35140700    9.94189600    5.54834100
 O                  3.27429600   10.12137400    3.50922200
 H                  3.69178400   12.59401900    3.44943300
 






