%mem=100GB
%nprocshared=24
#P B3LYP/Def2TZVPP SCRF(SMD,Solvent=THF) EmpiricalDispersion=GD3BJ 

opt of Geom

0,1 
C    0.0231959205    0.    0.0107180865
C    -0.0005196992    0.    1.4041366603
C    1.2129506202    0.    2.094930301
C    2.4235921192    0.    1.3993035477
C    2.4230535094    0.    0.0030271779
C    1.219285272    0.    -0.7045068273
H    -0.9447811226    0.    1.9377826145
H    1.2058551932    0.    3.1809937449
H    3.3635294598    0.    1.9430126217
H    3.3610017042    0.    -0.5445470039
H    1.2111043718    0.    -1.7891021299
Cl    -1.5056193484    0.    -0.8736067935



