%mem=43GB
%nprocshared=20
#p scrf=(solvent=n,n-DiMethylFormamide,smd)  b97d/gen pseudo=read opt freq=noraman

op

0 1
 C                  2.56475100    1.33438500   -0.77088900
 C                  3.50988100    1.21906200   -1.80725900
 H                  4.05946400    0.28558600   -1.93077600
 C                  3.74044000    2.29066000   -2.68437700
 H                  4.47167000    2.18586200   -3.48753600
 C                  3.03216200    3.49267600   -2.52319800
 H                  3.20953400    4.33020600   -3.20030000
 C                  2.08616000    3.62847300   -1.49587600
 C                  1.85836500    2.54687100   -0.63552700
 C                 -0.36267900    4.59826700    0.62480400
 C                 -0.24597300    3.27016600    0.19552600
 C                 -1.31249800    2.58847500   -0.43693400
 C                 -2.47859600    3.33867600   -0.71051800
 H                 -3.30701300    2.87148900   -1.23911800
 C                 -2.59901900    4.67735800   -0.30932900
 H                 -3.51559200    5.22489200   -0.53488300
 C                 -1.54978400    5.30400100    0.38054600
 H                 -1.64186800    6.34087200    0.70819700
 C                  3.27795100   -1.38005500   -0.04465200
 C                  2.95862100   -2.10715800   -1.21286400
 H                  2.10771800   -1.80777000   -1.82357100
 C                  3.73101400   -3.21398400   -1.59220800
 H                  3.47424200   -3.76492400   -2.49930500
 C                  4.81936400   -3.61921100   -0.79981200
 H                  5.41378900   -4.48833600   -1.08861900
 C                  5.13705400   -2.90454300    0.36652400
 H                  5.98014900   -3.21377800    0.98769400
 C                  4.37421300   -1.78621400    0.74276400
 H                  4.62954500   -1.24078500    1.65060300
 C                  2.79534400    0.69689100    2.00222300
 C                  1.95723600    0.71731600    3.13373000
 H                  0.95272000    0.29672200    3.06388400
 C                  2.40681800    1.28574700    4.33613600
 H                  1.74971300    1.29819500    5.20826400
 C                  3.69479900    1.84201400    4.41254100
 H                  4.04462700    2.28572500    5.34689700
 C                  4.53079100    1.83555800    3.28179100
 H                  5.52931400    2.27411800    3.33484400
 C                  4.08178100    1.27116800    2.07772600
 H                  4.72881000    1.27872900    1.19869100
 C                 -0.33077200    0.73267000   -2.48241300
 C                 -0.15073000    1.88287400   -3.27419500
 H                 -0.51719500    2.84980100   -2.92897300
 C                  0.51940300    1.78914900   -4.50467900
 H                  0.67222200    2.68860100   -5.10454900
 C                  0.99687300    0.54767600   -4.95653700
 H                  1.52067200    0.47845400   -5.91236000
 C                  0.79677500   -0.60388100   -4.17611900
 H                  1.15342300   -1.57471800   -4.52643600
 C                  0.14160000   -0.51695700   -2.93794800
 H                 -0.03261300   -1.42529100   -2.35624100
 C                 -2.91797000    0.28634900   -1.23465900
 C                 -3.19546400   -0.50996500   -2.36589200
 H                 -2.39710300   -0.79527600   -3.04779600
 C                 -4.50102600   -0.95485600   -2.61816200
 H                 -4.69663100   -1.57174600   -3.49792400
 C                 -5.55097900   -0.60307300   -1.75247400
 H                 -6.56874500   -0.94282200   -1.95568400
 C                 -5.28186900    0.18728400   -0.62470200
 H                 -6.08414500    0.46123400    0.06226700
 C                 -3.97255300    0.61659300   -0.35648200
 H                 -3.78068700    1.21411400    0.53272500
 O                  0.96160000    2.61664600    0.42981000
 P                  2.15585900   -0.00189400    0.42131900
 P                 -1.17937000    0.78278000   -0.84861200
 H                  1.52404800    4.55363500   -1.37032100
 H                  0.48615900    5.06714600    1.12365900
 Pd                -0.05159100   -0.63791700    0.63317900
 C                 -2.43265000   -2.61106500    0.34177000
 C                 -1.89838100   -1.72243200    1.47225600
 H                 -3.03296011   -2.01836801   -0.36928305
 H                 -1.57508878   -3.02929520   -0.20884585
 O                 -3.21600513   -3.68072418    0.85876825
 C                 -0.71200600   -1.98619800    2.23839300
 C                  0.48133400   -2.65381600    1.87637500
 H                 -0.65312500   -1.45144100    3.19208700
 C                 -2.89692600   -0.85486300    2.17498700
 C                 -4.25628800   -1.22563900    2.27285300
 C                 -2.49712400    0.36636500    2.77075600
 C                 -5.18457000   -0.39756200    2.92441000
 H                 -4.59642100   -2.16560900    1.83731800
 C                 -3.42274700    1.19843300    3.41178200
 H                 -1.45400400    0.67804700    2.68161800
 C                 -4.77716900    0.82224300    3.48691600
 H                 -6.23073200   -0.70571700    2.98232100
 H                 -3.09091100    2.14709900    3.83992100
 H                 -5.50349000    1.47303900    3.97820100
 C                  1.59593300   -2.65430500    2.89955700
 H                  1.58030300   -3.62762000    3.42581900
 H                  2.57921300   -2.57920200    2.41202900
 H                  1.49590700   -1.85290100    3.64332700
 C                  0.62323100   -3.73510200    0.81708900
 H                  1.48752900   -4.37238800    1.06122600
 H                 -0.27885200   -4.36164200    0.76623000
 H                  0.77724900   -3.32517600   -0.18850800
 C                 -4.36559694   -4.15357367    0.07199950
 O                 -4.57936702   -3.57822457   -1.01548958
 O                 -4.95619666   -5.07796833    0.67241047

C O P H 0
6-31g(d)
****
pd 0
SDD
****

pd 0
SDD






