%chk=Before.chk
%nprocshared=8
%mem=22GB
#p opt=(noeigentest) iop(1/8=10) freq=noraman wb97xd/6-311G** nosymm scrf=(smd,solvent=butanone)

Dimer

0 1
 Al                 2.73669000    9.18352200    0.97764000
 N                  2.03048300   11.02976800    0.89854500
 O                  4.39020400    9.40347800    0.48103200
 O                  1.61681300    8.33849500   -0.05238000
 O                  1.29914700   12.24335400    4.59222800
 C                  3.21442400   11.95029700    1.02930600
 H                  3.62273200   11.78979100    2.02935600
 H                  2.86128600   12.97980800    0.97581900
 C                  4.28237000   11.73536700   -0.01237400
 C                  4.83864900   10.46806000   -0.21518200
 C                  5.86452700   10.28547700   -1.15393700
 C                  6.30377900   11.38825400   -1.87646400
 H                  7.09493300   11.24757000   -2.60888800
 C                  5.75907800   12.66357500   -1.70281000
 C                  4.74420100   12.81457200   -0.76586700
 H                  4.29482000   13.79135000   -0.61037900
 C                  1.45792200   11.13954800   -0.49092800
 H                  2.26969500   10.89550000   -1.18270100
 H                  1.18626200   12.17706300   -0.68674300
 C                  0.29755800   10.21634300   -0.72983800
 C                  0.45266100    8.84055400   -0.51823500
 C                 -0.60587000    7.96287000   -0.79077500
 C                 -1.79969900    8.49297600   -1.26847600
 H                 -2.62130200    7.81213500   -1.47647100
 C                 -1.98394900    9.86167200   -1.47810500
 C                 -0.91871900   10.71008100   -1.19769000
 H                 -1.02703200   11.78100900   -1.34665300
 C                  0.99461800   11.29130200    1.97938300
 H                  1.32610900   10.77507600    2.87699700
 H                  0.07874600   10.80484100    1.64326600
 C                  0.75645700   12.73776600    2.33887200
 C                  1.04012000   13.17016100    3.64064200
 C                  0.98091200   14.53530000    3.96496500
 C                  0.56623600   15.43348700    2.99164000
 H                  0.51442700   16.48994500    3.24388600
 C                  0.18061300   15.02017700    1.71275300
 C                  0.27848600   13.66884700    1.41104100
 H                 -0.02277500   13.33090500    0.42563700
 O                  1.99766800    9.19718200    4.49994700
 C                  2.43136100    9.67220200    5.78180300
 C                 -0.42884100    6.49035100   -0.55309200
 H                  0.41233500    6.09497300   -1.12971600
 H                 -0.21444000    6.28547100    0.50030100
 H                 -1.32918900    5.94011200   -0.83406300
 C                  1.33753700   14.98217300    5.35562700
 H                  0.64285200   14.56195500    6.09066400
 H                  2.34126100   14.64482300    5.63938000
 H                  1.30473600   16.07022500    5.43753200
 C                 -0.32351300   16.01818700    0.70245900
 H                 -1.22226200   16.52774300    1.06323600
 H                  0.42614800   16.78917500    0.49906600
 H                 -0.57005400   15.53197000   -0.24413400
 C                 -3.29116600   10.39215100   -2.00666800
 H                 -3.39159600   10.19858700   -3.07986900
 H                 -4.14207600    9.91707800   -1.51060800
 H                 -3.37053600   11.47112200   -1.85522700
 C                  6.44380700    8.91514000   -1.36040500
 H                  6.87836800    8.52442300   -0.43556200
 H                  5.67171000    8.20462600   -1.67079300
 H                  7.22214800    8.93363300   -2.12572700
 C                  6.25984200   13.82799500   -2.51751400
 H                  7.32991100   13.99162600   -2.35730000
 H                  6.11484100   13.65261700   -3.58796100
 H                  5.73617500   14.74977000   -2.25448200
 H                  1.67488200   10.37551000    6.11919900
 C                  3.78273400   10.33331100    5.66803300
 O                  3.47737100   12.18296500    5.91794900
 H                  2.06383300   12.44398800    5.19265500
 H                  2.48990300    8.82798000    6.46965100
 C                  4.07262200   11.50872800    4.85886500
 H                  4.51823200   10.07228700    6.41830600
 H                  3.53900500   11.57175100    3.90678300
 H                  5.13637300   11.70640900    4.71008900
 O                  2.73940100    8.44417600    2.58289200
 C                  3.04707500    8.82211400    3.77346400
 O                  4.17273100    8.86333800    4.24892500






