%chk=Before.chk
%nprocshared=8
%mem=22GB
#p opt=(noeigentest) iop(1/8=10) freq=noraman wb97xd/6-311G** nosymm scrf=(smd,solvent=butanone)

Dimer

0 1
 Al                 2.74003400    9.20528100    0.95530700
 N                  2.03434100   11.05111000    0.88619700
 O                  4.40792400    9.40585300    0.52080400
 O                  1.66172100    8.35262500   -0.10195600
 O                  1.29708100   12.24304400    4.60815300
 C                  3.22339500   11.96695900    1.01238900
 H                  3.62324900   11.81985000    2.02323800
 H                  2.86779700   12.99871500    0.94768300
 C                  4.29290500   11.73364900   -0.02476800
 C                  4.85021400   10.46047800   -0.20588100
 C                  5.87532900   10.25919500   -1.14437300
 C                  6.31521400   11.35026500   -1.88862100
 H                  7.10645100   11.19588900   -2.62065000
 C                  5.77136000   12.63081900   -1.73643000
 C                  4.75500400   12.79955300   -0.80056300
 H                  4.30643000   13.78121200   -0.66228700
 C                  1.45562900   11.16056900   -0.50233000
 H                  2.27059800   10.93021400   -1.19735400
 H                  1.17265400   12.19829600   -0.68586800
 C                  0.30269500   10.22537700   -0.73647600
 C                  0.47845900    8.84726300   -0.54076400
 C                 -0.57408600    7.95654700   -0.80339700
 C                 -1.78447400    8.47627900   -1.25692800
 H                 -2.60221100    7.78603400   -1.45775000
 C                 -1.98949500    9.84624300   -1.45235600
 C                 -0.92973200   10.70784700   -1.17953400
 H                 -1.05517400   11.77995700   -1.31886300
 C                  1.00292700   11.31418400    1.97201500
 H                  1.33884500   10.80868000    2.87425600
 H                  0.08603500   10.82078700    1.63607500
 C                  0.76585600   12.75976400    2.34267000
 C                  1.03757900   13.16543100    3.66602800
 C                  0.96071300   14.53577300    4.00458800
 C                  0.55828500   15.45064600    3.03876600
 H                  0.49634100   16.50407300    3.30815700
 C                  0.19695600   15.05659500    1.74450400
 C                  0.30228800   13.70795900    1.42167200
 H                  0.01492800   13.38707200    0.42458400
 O                  1.94258100    9.19297000    4.50040100
 C                  2.43375200    9.67125500    5.77545000
 C                 -0.37415800    6.48267900   -0.58133400
 H                  0.46449300    6.10091000   -1.17433800
 H                 -0.14315700    6.26874900    0.46889400
 H                 -1.27249300    5.92121700   -0.85497400
 C                  1.29975500   14.95707000    5.40926900
 H                  0.64875600   14.45678100    6.13402900
 H                  2.32844400   14.67450800    5.66767000
 H                  1.18943000   16.03733500    5.53512600
 C                 -0.29242800   16.07012600    0.74031400
 H                 -1.20045600   16.57399100    1.09196400
 H                  0.45865900   16.84868600    0.56088200
 H                 -0.52126500   15.59853500   -0.22055000
 C                 -3.31202300   10.36472300   -1.95847800
 H                 -3.42969400   10.17427000   -3.03252400
 H                 -4.15242400    9.87838600   -1.45085400
 H                 -3.40232500   11.44432000   -1.80211500
 C                  6.45317900    8.88313800   -1.32870900
 H                  6.88752800    8.50388300   -0.39667800
 H                  5.68046500    8.16677700   -1.63123800
 H                  7.23438700    8.88770600   -2.09433700
 C                  6.27375300   13.78181800   -2.57161300
 H                  7.34634700   13.94750300   -2.41656300
 H                  6.12774400   13.59126200   -3.64142400
 H                  5.75207200   14.71134300   -2.32320200
 H                  1.78014100   10.47682300    6.09742600
 C                  3.85776400   10.10007500    5.44801000
 O                  3.43630200   12.27900100    5.90131300
 H                  2.15198100   12.41688300    5.22514900
 H                  2.40893900    8.83017800    6.47355700
 C                  4.01607800   11.52803900    4.92282500
 H                  4.57257100    9.86543200    6.23628700
 H                  3.52967300   11.59394500    3.92629400
 H                  5.09416400   11.71957600    4.74320800
 O                  2.70943700    8.43760700    2.59131100
 C                  2.95584600    8.86470000    3.75529200
 O                  4.11780300    9.01562900    4.27674400






