%mem=73GB
%nprocshared=24
#p freq=noraman scrf=(solvent=n,n-DiMethylFormamide,smd)  b97d/gen pseudo=read opt

op

0 1
 C                 -1.66659300    1.70265300    2.16428500
 C                 -1.28989100    1.83580800    3.51632600
 H                 -0.88806600    0.97613100    4.04902700
 C                 -1.39584700    3.06371200    4.18310500
 H                 -1.08328000    3.14116100    5.22549400
 C                 -1.89712200    4.18646400    3.50514400
 H                 -1.98951100    5.14610900    4.01670500
 C                 -2.27221100    4.08261600    2.16045300
 C                 -2.14690500    2.85071700    1.49981300
 C                 -2.98546600    4.70704500   -1.10864100
 C                 -2.06963700    3.73593100   -0.68748700
 C                 -0.71598600    3.75949900   -1.10732100
 C                 -0.29762100    4.85350000   -1.89514500
 H                  0.74370100    4.92480100   -2.20544900
 C                 -1.20287200    5.84573900   -2.30136600
 H                 -0.85040200    6.67748200   -2.91323100
 C                 -2.55305000    5.76087000   -1.92864200
 H                 -3.26554500    6.52094500   -2.25328100
 C                 -0.48333000   -1.01716700    2.21549600
 C                  0.69174400   -1.49827100    1.60628400
 H                  0.92652600   -1.20793000    0.58159400
 C                  1.55020100   -2.35960400    2.30680400
 H                  2.45808900   -2.71954100    1.82426500
 C                  1.22827800   -2.76287500    3.61275100
 H                  1.89653300   -3.43419600    4.15635000
 C                  0.03765300   -2.31645700    4.21370300
 H                 -0.22577000   -2.64193600    5.22211000
 C                 -0.82062600   -1.45421800    3.51552400
 H                 -1.75195400   -1.12388000    3.97732700
 C                 -3.24455100   -0.62723500    1.59630200
 C                 -3.40652300   -2.02226200    1.45030700
 H                 -2.57739700   -2.62955600    1.08827400
 C                 -4.63348900   -2.62185900    1.76372300
 H                 -4.75231900   -3.69976500    1.64509200
 C                 -5.71303000   -1.83890200    2.20673700
 H                 -6.66914300   -2.31028800    2.44202700
 C                 -5.56121100   -0.44897100    2.33429200
 H                 -6.39524500    0.16690400    2.67725500
 C                 -4.33107100    0.15761900    2.03283500
 H                 -4.22101100    1.23497900    2.15912800
 C                  1.12307000    2.73254500    0.94645800
 C                  1.08921000    4.03141500    1.48911800
 H                  0.58701300    4.83733100    0.95325500
 C                  1.69246000    4.28415100    2.73119400
 H                  1.65063900    5.28960300    3.15455600
 C                  2.34145400    3.25127800    3.42931000
 H                  2.80523500    3.45415000    4.39665800
 C                  2.38821600    1.95847100    2.88191900
 H                  2.89271500    1.14832700    3.41180400
 C                  1.77817300    1.70050700    1.64604600
 H                  1.82335300    0.70121500    1.22084600
 C                  1.86146900    2.54782700   -1.83910400
 C                  3.17699500    2.38971800   -1.35331300
 H                  3.36021800    2.22407400   -0.29292400
 C                  4.27134200    2.43773900   -2.23242200
 H                  5.27961900    2.30437400   -1.83641500
 C                  4.07171600    2.65812600   -3.60350300
 H                  4.92369700    2.69561000   -4.28505000
 C                  2.76661600    2.83930500   -4.09247100
 H                  2.59724300    3.02967800   -5.15403700
 C                  1.67054500    2.78019600   -3.22062900
 H                  0.67052800    2.95187500   -3.61467300
 O                 -2.53865700    2.73024300    0.16170300
 P                 -1.58215400    0.09647100    1.25251600
 P                  0.41080200    2.34823400   -0.70498400
 H                 -2.64953000    4.94843400    1.61664400
 H                 -4.01940400    4.63923300   -0.76865500
 Pd                -0.84563300    0.39250100   -0.95183200
 C                 -0.95827200   -2.56700900   -1.95663000
 C                 -1.97552700   -1.44489000   -2.06566700
 H                 -1.23676800   -3.33598600   -2.71015800
 H                  0.04142900   -2.20451600   -2.22734300
 O                 -0.97399400   -3.12770300   -0.64458600
 C                 -1.71126800   -0.29837300   -2.86830700
 C                 -0.42771900    0.24335500   -3.11433100
 H                 -2.56759100    0.31016300   -3.16929300
 H                 -0.40350200    1.16679900   -3.68862800
 H                  0.48305400   -0.35952900   -3.14465500
 C                 -3.38742300   -1.74857400   -1.74460800
 C                 -4.34276200   -0.68891700   -1.58192400
 C                 -3.83622300   -3.06666700   -1.63604600
 C                 -5.68135400   -0.95201400   -1.37350400
 H                 -3.99095600    0.34307400   -1.58946000
 C                 -5.20692900   -3.37064400   -1.41198200
 H                 -3.13246800   -3.89510700   -1.70709400
 C                 -6.15993700   -2.29433600   -1.28832700
 H                 -6.38963100   -0.13179300   -1.23734200
 H                 -0.11982100   -3.61446800   -0.54584700
 C                 -5.66418200   -4.71647900   -1.27883100
 C                 -7.00291200   -4.98750200   -1.03180600
 H                 -4.93770700   -5.52773800   -1.36924900
 H                 -7.34180500   -6.02025300   -0.92656300
 C                 -7.94217800   -3.92341700   -0.91361100
 C                 -7.52782600   -2.60382500   -1.04108800
 H                 -8.99261200   -4.15044100   -0.71948900
 H                 -8.24274600   -1.78320900   -0.94363400
 C                  3.92404020    0.10233403   -2.01344453
 C                  2.99470971   -0.88728955   -2.17762019
 H                  3.87221713    1.01029741   -2.62073851
 H                  4.72003836    0.04939975   -1.26779001
 H                  2.24985435   -0.73239381   -2.96724747
 C                  2.85965724   -2.17312467   -1.52700514
 C                  1.90698945   -3.09096558   -2.06516543
 H                  1.30690043   -2.68854462   -2.92177464
 C                  3.62848662   -2.56171288   -0.33592755
 C                  3.99991077   -1.64887082    0.66707866
 C                  4.04411338   -3.93077043   -0.15475204
 C                  4.75145426   -2.03649184    1.81061504
 H                  3.70173252   -0.60277164    0.57940450
 C                  4.75795459   -4.34589640    0.95380500
 H                  3.81727008   -4.65069778   -0.94130424
 C                  5.14390390   -3.42039097    1.97023868
 H                  5.06801355   -5.38978203    1.04668068
 O                  1.70801295   -4.29083090   -1.71959368
 C                  5.90673542   -3.80458768    3.11004013
 C                  6.27090160   -2.86907251    4.07177499
 H                  6.19963783   -4.85299491    3.21397772
 H                  6.85436448   -3.17419637    4.94323229
 C                  5.88035828   -1.50708070    3.92329767
 C                  5.14093882   -1.10081147    2.82061000
 H                  6.16899196   -0.77785565    4.68413062
 H                  4.84486363   -0.05466948    2.70632478

C O P H 0
6-31g(d)
****
pd 0
SDD
****

pd 0
SDD








