%nprocshared=36
%mem=41GB
#p irc=(lqa,tight,calcfc,stepsize=10,maxpoints=200) b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(conver=6,maxcyc=512) int(grid=coarse)

IRC with loosened settings

1 1
 P                  0.17726000    0.15038500   -3.25751700
 Au                -0.11301500    0.05504700   -0.90739800
 C                  0.08604900    1.84874800   -3.94214600
 H                  0.85972300    2.46974100   -3.48215800
 H                  0.23543400    1.82348400   -5.02629600
 H                 -0.89350900    2.28060300   -3.71926000
 C                 -1.07817000   -0.81159400   -4.18728800
 H                 -2.07563500   -0.42656700   -3.95810700
 H                 -0.89344200   -0.72560700   -5.26292800
 H                 -1.02716100   -1.86300900   -3.89141000
 C                  1.79956500   -0.50401500   -3.80856900
 H                  1.89224400   -1.55126700   -3.50821800
 H                  1.88523000   -0.42661900   -4.89718800
 H                  2.60250800    0.07101700   -3.33917100
 C                 -0.26777600   -0.01093000    1.10431500
 C                  0.08311000   -1.21466700    1.88216500
 H                  0.88365600   -1.78726700    1.40322800
 C                 -0.76218800    1.14892200    1.88278100
 H                 -0.23548800    2.05439500    1.55575800
 H                 -1.80333200    1.32712200    1.55143500
 N                 -0.62212500   -0.12871500    3.98534800
 C                 -0.74001900   -0.22132400    5.44751900
 H                  0.22691100    0.00001500    5.91194900
 H                 -1.48969200    0.48973200    5.79590600
 H                 -1.05066500   -1.23405700    5.70907100
 C                  0.40015900   -0.96099700    3.36084300
 H                  0.52432700   -1.89702700    3.90208900
 C                  1.72128200   -0.07096700    3.38584400
 O                  2.79962500   -0.67016200    3.34674300
 O                  1.46675800    1.17745300    3.34082800
 C                 -0.72608900    1.03392100    3.38129700
 H                 -1.11664400    1.87180900    3.95193000
 H                 -0.82358300   -1.84573200    1.76249000

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


