%nprocshared=24
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Direct TS smaller step

1 1
 P                 -0.16240621    0.00311218   -3.20056704
 Au                 0.09594882   -0.05298717   -0.87754158
 C                 -1.76881523    0.70741914   -3.74582054
 H                 -1.90157455    1.70799689   -3.32500140
 H                 -1.79460094    0.76914048   -4.83873346
 H                 -2.58801018    0.07070098   -3.39850694
 C                 -0.08483007   -1.64197226   -4.01361750
 H                 -0.87095024   -2.28815260   -3.61278658
 H                 -0.22225045   -1.52418302   -5.09291293
 H                  0.88852089   -2.10082886   -3.81942084
 C                  1.10756448    0.99491984   -4.07543503
 H                  2.08196688    0.51257246   -3.95793576
 H                  0.85610911    1.05963994   -5.13912470
 H                  1.15716672    1.99910547   -3.64687982
 C                  0.30493969   -0.14275037    1.20108038
 C                 -0.04706452   -1.30255140    2.08546296
 H                  0.66022924   -2.11843983    1.89704128
 C                 -1.01558645    1.35473475    1.93379484
 H                 -0.14582727    1.98835607    2.07155197
 H                 -1.72186047    1.75066844    1.21094341
 N                 -0.93429743    0.01274795    3.94413366
 C                 -1.54966110   -0.46377206    5.19418654
 H                 -0.79588717   -0.44576183    5.98343638
 H                 -2.36858821    0.19971065    5.46990345
 H                 -1.91801459   -1.48638457    5.06631415
 C                  0.25197264   -0.71356860    3.48508578
 H                  0.53326139   -1.42984306    4.25412318
 C                  1.48619375    0.16270363    3.14698998
 O                  2.34097047    0.57545521    3.88739784
 O                  1.49626915    0.36966001    1.78481508
 C                 -1.59153051    0.80118071    3.10846308
 H                 -2.64338372    0.95393043    3.34524954
 H                 -1.06710101   -1.66714177    1.95924798

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



