%nprocshared=8
%mem=22GB
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=(xqc,maxcyc=512)

Direct TS

0 1
 P                  0.07106399   -1.45371026   -3.05943638
 Au                 0.18287376   -0.31480187   -1.06644873
 C                 -1.62508132   -1.37044153   -3.75370447
 H                 -1.91678398   -0.31938249   -3.81465886
 H                 -1.65470943   -1.82640157   -4.74824168
 H                 -2.31789199   -1.89189689   -3.08770373
 C                  0.47691722   -3.24637132   -3.02026914
 H                 -0.17494961   -3.75098408   -2.30128859
 H                  0.33383063   -3.69147906   -4.01098133
 H                  1.51579891   -3.38649742   -2.70707219
 C                  1.13998516   -0.77124162   -4.38890929
 H                  2.18700415   -0.81028917   -4.07623725
 H                  1.00925618   -1.35236210   -5.30790841
 H                  0.86606352    0.27090401   -4.57668288
 C                  0.07502156    0.70090046    0.84873728
 C                  0.96852879   -0.11210071    1.86916699
 H                  1.85615870   -0.53461955    1.40287775
 C                 -1.29235419    1.02799137    1.38455126
 H                 -2.20947152    0.81056153    0.85678868
 C                  0.37050513   -0.99393567    2.91950261
 C                 -0.60795841   -1.94042793    2.58310929
 C                  0.81285156   -0.92836936    4.24808537
 C                 -1.13201407   -2.79962500    3.54962899
 H                 -0.96091963   -1.98951473    1.55644106
 C                  0.28811147   -1.78467225    5.22060160
 H                  1.58229219   -0.21071589    4.52031221
 C                 -0.68947933   -2.71985868    4.87416803
 H                 -1.89119609   -3.52726029    3.27397351
 H                  0.64283832   -1.72063453    6.24594380
 H                 -1.10581437   -3.38191613    5.62906391
 N                  0.12405441    2.07677610    2.82411050
 C                  0.56957772    2.68054231    4.05905949
 H                  1.46929042    3.28032843    3.87618794
 H                 -0.21061189    3.34794079    4.43750441
 H                  0.80373524    1.94264594    4.84143462
 C                  1.01419748    1.36747529    1.95817457
 H                  1.92994094    1.89612812    1.69845439
 C                 -1.19295480    1.76812692    2.50633281
 H                 -1.98411845    2.15417357    3.13887686
 C                 -0.41930104    3.05364368   -1.41751059
 O                  0.52269436    2.78181081   -0.55204107
 O                 -1.37188255    2.31277308   -1.68807571
 C                 -0.26284877    4.41492057   -2.08419020
 H                  0.77863869    4.58393601   -2.37471555
 H                 -0.91519597    4.48900977   -2.95702072
 H                 -0.53548627    5.20079220   -1.36990824
 H                  0.35221399    1.71909213    0.00850910

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


