%nprocshared=8
%mem=22GB
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=(xqc,maxcyc=512)

Direct TS

0 1
 P                  0.06293078   -1.16201311   -3.42204089
 Au                 0.17295218   -0.42629480   -1.18153636
 C                 -0.90614505   -0.06376321   -4.53442294
 H                 -0.45201468    0.92972935   -4.56686518
 H                 -0.93206229   -0.47988145   -5.54752839
 H                 -1.92890993    0.02362850   -4.15321310
 C                 -0.76115991   -2.79604810   -3.60360633
 H                 -1.76407028   -2.74657962   -3.17048875
 H                 -0.83339500   -3.06948080   -4.66031252
 H                 -0.18584568   -3.55711864   -3.06821486
 C                  1.67169986   -1.36770773   -4.28756668
 H                  2.28366398   -2.09579858   -3.74829521
 H                  1.51148824   -1.71778294   -5.31361965
 H                  2.20312905   -0.41190459   -4.30679497
 C                  0.26053647    0.11455362    0.83549620
 C                  0.58778322   -0.95610907    1.86775345
 H                  0.92733377   -1.89022714    1.42272498
 C                 -0.48551498    1.36123496    1.38788438
 H                 -0.23151458    2.30483498    0.65396875
 H                 -1.57582182    1.37371879    1.44335383
 C                 -0.14377245   -1.13886199    3.16378696
 C                 -1.54414013   -1.13214487    3.19378645
 C                  0.55537387   -1.34925779    4.36316842
 C                 -2.23237566   -1.33096545    4.39358983
 H                 -2.09289590   -0.97062837    2.26988069
 C                 -0.12874562   -1.54415647    5.56361030
 H                  1.64188515   -1.36704412    4.35013036
 C                 -1.52605766   -1.53330463    5.58183789
 H                 -3.31817324   -1.32547990    4.39952246
 H                  0.42767312   -1.70284563    6.48307793
 H                 -2.06066455   -1.68372468    6.51520758
 N                  1.44690688    1.25544105    2.61387123
 C                  2.54567444    1.59322179    3.51966210
 H                  3.45208106    1.72698275    2.92338155
 H                  2.31222826    2.51568198    4.05044080
 H                  2.69096659    0.77375377    4.22743537
 C                  1.57574101    0.17762959    1.63829614
 H                  2.57630471    0.02624505    1.25295549
 C                  0.28041261    1.80171744    2.58073160
 H                 -0.01604121    2.52424718    3.33287484
 C                 -0.76910745    3.37438892   -0.97524628
 O                 -0.70627795    4.44164714   -1.66352282
 O                 -0.00651971    3.11252513    0.04373736
 C                 -1.86359787    2.46545219   -1.47569031
 H                 -2.47677545    2.92308510   -2.25185088
 H                 -1.40234362    1.54785028   -1.86004652
 H                 -2.48900462    2.17948360   -0.62298094

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD

