%nprocshared=24
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Direct TS smaller step

1 1
 P                  0.19801117   -0.51284651   -2.93657241
 Au                -0.26081875   -0.29806793   -0.66827578
 C                 -1.26202906   -0.98986619   -3.94008461
 H                 -2.03712454   -0.22428360   -3.84602385
 H                 -0.97708706   -1.09359117   -4.99212439
 H                 -1.65959242   -1.94097762   -3.57487451
 C                  1.45835049   -1.79563660   -3.29957674
 H                  1.10983386   -2.76369010   -2.92912201
 H                  1.63257789   -1.85837078   -4.37865800
 H                  2.39342440   -1.54128115   -2.79289562
 C                  0.83985768    1.01572431   -3.72243961
 H                  1.77121389    1.31215465   -3.23198651
 H                  1.02803521    0.84006871   -4.78667035
 H                  0.10927877    1.82152140   -3.60938775
 C                 -0.83199077   -0.20871646    1.40749926
 C                 -1.48678512   -1.40978237    2.08204671
 H                 -1.98352865   -2.07597545    1.37236890
 C                 -1.26883247    1.04458246    1.70378531
 H                 -2.16910175    1.22303791    2.29870967
 N                  0.56795634   -1.11178612    3.31607918
 C                  0.16299108   -0.20439375    4.37312855
 H                 -0.12179444   -0.79140790    5.24720611
 H                  1.00472898    0.44249477    4.62620895
 H                 -0.68673341    0.42152475    4.05601949
 C                 -0.32612710   -2.17710558    2.82363141
 H                 -0.64975252   -2.87975575    3.58772782
 C                  0.56593417   -2.78979110    1.75695195
 O                  0.54971962   -3.85415001    1.21336362
 O                  1.44639677   -1.77075871    1.38543007
 C                  1.11701545   -0.68205118    2.16198987
 H                  1.76229710    0.18185269    2.08727558
 H                 -2.21969275   -1.11123595    2.84048425
 C                 -0.54667554    2.30355988    1.18894046
 C                 -0.78180889    2.76135326   -0.10782820
 C                  0.34237510    2.98625444    2.01903999
 C                 -0.12748317    3.90120489   -0.57453781
 H                 -1.48219370    2.22246461   -0.76227602
 C                  0.99623358    4.12703634    1.55267574
 H                  0.52767879    2.62568214    3.04118440
 C                  0.76156599    4.58450623    0.25606885
 H                 -0.31229089    4.26174230   -1.59686622
 H                  1.69684524    4.66534267    2.20753743
 H                  1.27731751    5.48324834   -0.11211497

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



