%nprocshared=24
%mem=41GB
%chk=ZZtemp2.chk
#p opt=(modredundant,loose) b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Loose preopt

1 1
 P                 -1.16624697    0.08319102   -3.32915624
 Au                -0.60019178    0.03873198   -1.04904795
 C                 -2.58201277    1.18426550   -3.72366203
 H                 -2.34151207    2.20872317   -3.42564702
 H                 -2.79513358    1.15711150   -4.79724248
 H                 -3.46549841    0.85606875   -3.16885230
 C                 -1.64605524   -1.55011647   -4.01863138
 H                 -2.50371212   -1.94170887   -3.46428770
 H                 -1.91012279   -1.45375391   -5.07689997
 H                 -0.81197133   -2.25004136   -3.91449667
 C                  0.18893457    0.66757254   -4.42219731
 H                  1.05314631    0.00511617   -4.31938507
 H                 -0.14054365    0.67550351   -5.46623195
 H                  0.48361552    1.67862552   -4.12680058
 C                 -0.06913410   -0.01407966    0.97334363
 C                 -0.93663333   -0.66563594    1.86003041
 H                 -1.30154546   -1.64053908    1.53658664
 C                  1.09413699    0.61584583    1.38429386
 H                  1.72463193    1.13775310    0.67399683
 H                  1.27306849    0.85634000    2.43311581
 C                 -1.41680609   -0.27240939    3.15581242
 C                 -0.93367454    0.84930572    3.87477391
 C                 -2.45558367   -1.04970045    3.73545515
 C                 -1.49836427    1.20232330    5.09358947
 H                 -0.10793198    1.43065444    3.49704330
 C                 -3.01574190   -0.69071155    4.95229982
 H                 -2.82396684   -1.92241026    3.20294727
 C                 -2.54003085    0.43926899    5.63337381
 H                 -1.11497582    2.06718481    5.62556427
 H                 -3.81782121   -1.28539514    5.37820777
 H                 -2.97297067    0.71403756    6.59081105
 C                  2.80087207   -0.91138540    0.70322670
 C                  2.98945368   -0.38548210   -0.58899397
 N                  3.67300211   -0.25022024    1.57060895
 H                  2.05327561   -1.59327814    1.06958565
 O                  4.14158746    0.54554272   -0.40353676
 O                  2.51976442   -0.53429243   -1.69782959
 C                  3.73864161   -0.47212991    3.01422191
 H                  4.52981090    0.14842333    3.43564125
 H                  2.77814418   -0.20610136    3.46033535
 H                  3.95181121   -1.52836962    3.19951501
 C                  4.43897766    0.56155865    0.87556228
 H                  5.22534816    1.18896575    1.27030161

18 32 F

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nprocshared=24
%mem=41GB
%chk=ZZtemp2.chk
#p opt=(modredundant,calcfc,ts,noeigentest,maxstep=10) freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm guess=read empiricaldispersion=gd3 geom=checkpoint scf=maxcyc=512

Opt freq

1 1

18 32 A

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


