%nprocshared=24
%mem=41GB
%chk=ZZtemp2.chk
#p opt=(modredundant,loose) b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Loose preopt

1 1
 P                 -0.10142266    0.04132746   -4.06066534
 Au                -0.13897063    0.09607005   -1.71882481
 C                 -1.69229160    0.51768918   -4.84837144
 H                 -1.98477764    1.51375207   -4.50454259
 H                 -1.59209700    0.52563177   -5.93860677
 H                 -2.47295088   -0.19165646   -4.55916412
 C                  0.28852742   -1.61506590   -4.75669827
 H                 -0.45788786   -2.34028064   -4.42005447
 H                  0.29040111   -1.57815822   -5.85075907
 H                  1.27336212   -1.93291683   -4.40289754
 C                  1.13956886    1.15813108   -4.82768457
 H                  2.13940771    0.88302408   -4.47987614
 H                  1.09909275    1.08344131   -5.91963410
 H                  0.93890278    2.19133751   -4.53006619
 C                 -0.27366855    0.17562015    0.36183631
 C                 -1.29270366   -0.48936747    0.96722507
 H                 -1.90583414   -1.13372572    0.33671198
 C                  0.82751584    0.89938315    1.10880210
 H                  1.74510488    0.96408319    0.51793258
 H                  0.58644367    1.90775475    1.46449824
 C                 -1.82150052   -0.35674947    2.34574420
 C                 -1.99731051    0.92793470    2.88603013
 C                 -2.28688777   -1.46355514    3.07847625
 C                 -2.62284248    1.10804651    4.11725937
 H                 -1.69195225    1.78837807    2.29857365
 C                 -2.89840879   -1.28488901    4.32142480
 H                 -2.19681666   -2.46434416    2.66272175
 C                 -3.07643847    0.00120548    4.83925685
 H                 -2.77384962    2.11156064    4.50409223
 H                 -3.25893759   -2.14757277    4.87466035
 H                 -3.57514547    0.13969223    5.79406288
 C                  1.29455333   -0.17698414    2.73500551
 C                  1.73111615    0.74146437    3.86252354
 N                  2.55082770   -0.87131967    2.44857801
 H                  0.49922732   -0.86201155    3.02683951
 O                  3.16407478    0.81733490    3.73445637
 O                  1.15581877    1.33361345    4.71325495
 C                  2.63533175   -2.07324428    1.61690886
 H                  3.67471772   -2.39286844    1.55956976
 H                  2.03213984   -2.84931551    2.09160220
 H                  2.25830441   -1.86224094    0.61513831
 C                  3.52525212   -0.12943178    2.88016954
 H                  4.57934311   -0.31248390    2.70715157

18 32 F

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nprocshared=24
%mem=41GB
%chk=ZZtemp2.chk
#p opt=(modredundant,calcfc,ts,noeigentest,maxstep=10) freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm guess=read empiricaldispersion=gd3 geom=checkpoint scf=maxcyc=512

Opt freq

1 1

18 32 A

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


