%nprocshared=8
%mem=22GB
#p opt=(ts,calcfc,noeigentest,maxstep=10) freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Direct TS

1 1
 C                 -0.44329212   -1.13648595   -0.19001767
 C                  1.02437545   -1.53841738    0.23071019
 H                  1.86069564   -1.22417055   -0.37919256
 C                 -1.42795289   -1.22963627    0.94001305
 H                 -2.45705628   -0.93876169    0.76060599
 C                  0.12437182   -2.73708935   -0.65192358
 C                 -0.46654400   -3.85306538   -0.00529948
 C                  0.58458458   -2.88044371   -1.99769849
 C                 -0.52638885   -5.07320493   -0.67815528
 H                 -0.84998443   -3.76599959    0.99975523
 C                  0.51541520   -4.11383381   -2.62763202
 H                  1.01648828   -2.02503154   -2.51014319
 C                 -0.03954623   -5.22792710   -1.97845419
 H                 -0.96757821   -5.92367041   -0.16610148
 H                  0.89760078   -4.20887205   -3.63923470
 H                 -0.09736636   -6.19025522   -2.47870162
 N                  0.30288995   -1.91711616    2.49282730
 C                  0.59586746   -2.47521652    3.81187319
 H                  0.00724815   -1.95573977    4.57287483
 H                  0.35991303   -3.54465927    3.84735695
 H                  1.65521629   -2.33560491    4.03789416
 C                  1.28049948   -1.74323112    1.56484358
 H                  2.30721580   -1.82833477    1.90221017
 C                 -1.05264119   -1.58986032    2.16890312
 H                 -1.74381191   -1.63759520    2.99964324
 H                 -0.80727168   -0.94322414   -1.17944980
 P                  0.11446916    3.39813463   -0.16769285
 Au                -0.14337122    1.11366870   -0.30657243
 C                  0.28615881    3.97765108    1.57018877
 H                  1.15469272    3.50434044    2.03455200
 H                  0.40864858    5.06645177    1.60432838
 H                 -0.61055605    3.70068353    2.13123100
 C                 -1.29398861    4.33586979   -0.87413380
 H                 -2.20977338    4.03165985   -0.36071409
 H                 -1.12785304    5.40725092   -0.72368990
 H                 -1.40781633    4.12933461   -1.94138290
 C                  1.58332216    4.05149598   -1.04537911
 H                  1.51934850    3.83112969   -2.11435655
 H                  1.62796634    5.13264911   -0.89683735
 H                  2.48764617    3.58675542   -0.64285412

C H P N 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


