%nprocshared=24
%mem=41GB
%chk=TS2SM14_otherside.chk
#p opt=(modredundant,loose) b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Loose preopt

1 1
 P                 -1.05944899    0.08039679   -3.08789236
 Au                -0.70192499   -0.07316302   -0.78211133
 C                 -1.43541803    1.78193433   -3.65870672
 H                 -0.60452278    2.44437014   -3.40091232
 H                 -1.58652561    1.79051387   -4.74299545
 H                 -2.34089320    2.14109721   -3.16191270
 C                 -2.45644357   -0.95071124   -3.67828915
 H                 -3.38049803   -0.62607526   -3.19211838
 H                 -2.56071516   -0.85352032   -4.76380559
 H                 -2.27024095   -1.99722707   -3.42244053
 C                  0.38722781   -0.45574709   -4.07842830
 H                  0.62868988   -1.49490600   -3.83834309
 H                  0.16121510   -0.37076310   -5.14632366
 H                  1.24868644    0.17284410   -3.83686657
 C                 -0.07132007   -0.19409441    1.30118937
 C                 -1.38767516   -0.27522356    1.68877203
 H                 -1.91504771   -1.22490831    1.65522326
 C                  1.20078819   -0.17023599    1.66526679
 H                  1.47264395   -0.22388973    2.71850915
 H                 -1.99760733    0.62145831    1.75836034
 O                 -1.37988313   -0.38474262    3.99560972
 C                 -2.46896997    0.52082252    4.00586247
 H                 -2.21816737    1.49572496    3.55595098
 H                 -3.27664536    0.07676215    3.41371249
 H                 -2.85666966    0.70793596    5.02050422
 H                 -0.67606658    0.01599516    4.54676215
 O                  0.14478295    0.63659711    6.04572330
 C                 -0.10951684   -0.36946616    7.03452489
 H                 -0.19181104    0.06943033    8.03709037
 H                 -1.06083534   -0.83573762    6.76564927
 H                  0.66859213   -1.14255085    7.04199025
 H                  1.08701805    0.86264087    6.06600936
 C                  2.35061312   -0.06247655    0.64649766
 C                  2.91586840   -1.21865254    0.10778161
 C                  2.82688010    1.19094521    0.26224283
 C                  3.95760479   -1.12134983   -0.81446523
 H                  2.54067984   -2.20669437    0.41150626
 C                  3.86826675    1.28847372   -0.66101874
 H                  2.38136617    2.10229907    0.68660177
 C                  4.43375334    0.13260763   -1.19928959
 H                  4.40361623   -2.03263035   -1.23865635
 H                  4.24330105    2.27688608   -0.96411032
 H                  5.25509480    0.20907938   -1.92650800

16 21 F

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nprocshared=24
%mem=41GB
%chk=TS2SM14_otherside.chk
#p opt=(modredundant,calcfc,ts,noeigentest,maxstep=10) freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm guess=read empiricaldispersion=gd3 geom=checkpoint scf=maxcyc=512

Opt freq

1 1

16 21 A

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



