%nprocshared=24
%mem=41GB
%chk=TS2SM11.chk
#p opt=(modredundant,loose) b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Loose preopt

1 1
 P                 -0.32310995   -0.03349471   -4.02433492
 Au                 0.52240712    0.03061200   -1.84444618
 C                 -1.77453148    1.06319611   -4.26375732
 H                 -1.49178022    2.09524248   -4.03865648
 H                 -2.13058687    0.99918117   -5.29702315
 H                 -2.57441085    0.75984277   -3.58261424
 C                 -0.88949846   -1.69524442   -4.55679923
 H                 -1.68733178   -2.03740112   -3.89161421
 H                 -1.26389259   -1.65316896   -5.58497284
 H                 -0.05593886   -2.40053610   -4.50075431
 C                  0.88726500    0.49286531   -5.29813145
 H                  1.75930512   -0.16638235   -5.26932031
 H                  0.42941645    0.44974407   -6.29166564
 H                  1.21176550    1.51648284   -5.09081225
 C                  1.36781866    0.24195358    0.11194743
 C                  0.51004339   -0.63707892    0.79769047
 H                  0.71952404   -1.69821577    0.68962897
 C                  2.39716250    1.03659079    0.38608925
 H                  2.89183049    1.63011116   -0.37608910
 H                  2.78876439    1.11845147    1.39904156
 C                 -0.82265236   -0.29074179    1.26766531
 C                 -1.18504690    1.04998540    1.50700026
 C                 -1.73514656   -1.31934180    1.57178901
 C                 -2.43411948    1.34980808    2.03728530
 H                 -0.47556349    1.83990547    1.28333780
 C                 -2.99084917   -1.01310832    2.08926079
 H                 -1.45138507   -2.35432003    1.39891498
 C                 -3.33998828    0.32071732    2.32353716
 H                 -2.70450140    2.38254689    2.23392473
 H                 -3.69294343   -1.80928691    2.31692671
 H                 -4.31655075    0.55968014    2.73445814
 H                  2.41913505   -0.58910433    2.92525376
 H                  1.34353083   -1.83027329    3.19208390
 N                  1.43933676   -0.83450553    3.02059570
 N                  0.71078788   -0.02260626    3.89811272
 H                  0.50026307    0.90532924    3.55748767
 C                  0.74610613   -0.23923062    5.24760210
 O                  1.23057178   -1.22666814    5.77956503
 O                  0.15122336    0.78546283    5.90265728
 C                  0.09932199    0.64404661    7.33241134
 H                  1.10705447    0.56884507    7.75022006
 H                 -0.39612994    1.54465867    7.69579091
 H                 -0.47363079   -0.24433860    7.61244536

16 34 F

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD

--link1--
%nprocshared=24
%mem=41GB
%chk=TS2SM11.chk
#p opt=(modredundant,calcfc,ts,noeigentest,maxstep=10) freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm guess=read empiricaldispersion=gd3 geom=checkpoint scf=maxcyc=512

Opt freq

1 1

16 34 A

-C -H -P -N -O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD


