%nprocshared=24
%mem=41GB
#p opt freq b3lyp gen empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

-1 1
 O                  1.10763194    0.01251550   -1.30360005
 C                 -0.85795031    0.01320072    0.03512816
 S                  0.66430793    0.00230148   -0.07801072
 O                  1.31992872   -1.37425082    0.60328593
 O                  1.35110043    1.35258465    0.62480605
 F                 -1.33227307   -1.21730569   -0.25361374
 F                 -1.39906537    0.87359936   -0.85335858
 F                 -1.23649641    0.33894826    1.28935757

-C -H -N -P -O -S -F 0
6-31G(d)
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