%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                 -1.82741243    0.17971055    0.30018116
 C                 -2.75385246    1.08142662   -0.04423390
 H                 -3.66506958    0.79437737   -0.56439400
 H                 -2.63385212    2.13872719    0.18150883
 C                 -1.98006079   -1.29006629   -0.00661391
 H                 -1.14881260   -1.64676165   -0.63059178
 H                 -1.95288040   -1.88624726    0.91612062
 H                 -2.91799635   -1.50698333   -0.52773964
 C                 -0.55892481    0.56338972    1.02227818
 H                 -0.50461597    1.63941786    1.21603161
 H                 -0.48246564    0.03613480    1.98338881
 Si                 1.00271129    0.05154762   -0.00869726
 C                  1.42083804   -1.81180564    0.33289405
 H                  1.02334710   -2.41678908   -0.45507550
 H                  2.48258516   -1.93671140    0.37752135
 H                  0.98719803   -2.10964180    1.26463970
 C                  2.51009055    1.15787003    0.50846664
 H                  3.38022677    0.85103221   -0.03339451
 H                  2.29394700    2.18188544    0.28581350
 H                  2.68748712    1.05088031    1.55822073
 C                  0.63884070    0.29673662   -1.89842754
 H                  0.14831291    1.23579145   -2.04828923
 H                  1.55952834    0.28428463   -2.44347727
 H                  0.00798937   -0.49463320   -2.24578961

-C -H -Si 0
6-31G(d)
****







