%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                 -0.54280395   -0.10473058    0.02538388
 C                 -1.75612045   -0.70336906   -0.05247564
 H                 -1.83112671   -1.77073682   -0.05281849
 H                 -2.64213087   -0.10660888   -0.11381743
 C                 -0.43488399    1.43148304    0.02637533
 H                 -0.80954651    1.81594613   -0.89921428
 H                 -1.00988850    1.82890006    0.83651701
 H                  0.58976642    1.71697170    0.14251214
 O                  0.64133416   -0.90227182    0.10690002
 C                  1.79057573   -0.06993298   -0.07017592
 H                  2.67504637   -0.63293300    0.14346554
 H                  1.82561636    0.27942308   -1.08092935
 H                  1.73098610    0.76650973    0.59443876

-C -H -P -N -O 0
6-31G(d)
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