%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                  0.27672190   -0.48862641   -0.02759929
 C                  1.30816149    0.45019390    0.00733221
 C                  1.01078528    1.81263402    0.03069960
 C                 -0.31854622    2.23681734    0.01793979
 C                 -1.34967835    1.29817458   -0.01746254
 C                 -1.05205757   -0.06466477   -0.03983806
 H                  2.35562914    0.11561238    0.01774990
 H                  1.82371347    2.55266839    0.05886717
 H                 -0.55277151    3.31110659    0.03630997
 H                 -2.39744925    1.63216398   -0.02753486
 H                 -1.86511353   -0.80446281   -0.06754859
 C                  0.60536582   -1.99294016   -0.05276496
 H                  1.61935452   -2.31533644   -0.16584706
 C                 -0.38527895   -2.90980930    0.06782091
 H                 -0.15689617   -3.95501143    0.05068020
 H                 -1.39930706   -2.58741590    0.18055729

-C -H -P -N -O 0
6-31G(d)
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