%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                  2.54609041    0.03671712   -0.20949740
 C                  1.40190438    0.02594050   -0.93774578
 H                  1.49310742   -0.10831740   -2.01762181
 C                  3.64441286   -0.03545617    0.50488576
 H                  4.22429689    0.83978385    0.78077336
 H                  4.00733167   -1.00673907    0.83971099
 C                  0.02764815    0.02142198   -0.39432276
 C                 -0.22456148    0.02540351    0.98942678
 C                 -1.05040511    0.00347117   -1.29406452
 C                 -1.53405204    0.00555749    1.45912078
 H                  0.60842066    0.04200885    1.68655576
 C                 -2.36147298   -0.01840811   -0.81842190
 H                 -0.85799428    0.00095709   -2.36369086
 C                 -2.60560005   -0.01542959    0.55704975
 H                 -1.72308210    0.00504595    2.52847161
 H                 -3.18957899   -0.03749218   -1.52047667
 H                 -3.62628600   -0.03055456    0.92769330

C H 0
6-31G(d)
****



