%nprocshared=24
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 H                  0.24744462    1.03400461    2.35293375
 N                  0.33826995    0.02583562    2.29713216
 H                  0.22904196   -0.39268583    3.21403149
 N                 -0.43181872   -0.57102051    1.29178337
 H                 -0.23053166   -1.54984392    1.25452428
 C                 -0.10945201    0.04517160   -0.00331778
 O                 -0.10632983    1.29760099   -0.12571645
 O                  0.20166273   -0.78145584   -1.12794870
 C                  0.04655500   -0.02668140   -2.33258854
 H                  0.79140933    0.74052264   -2.37118891
 H                  0.15816308   -0.67493341   -3.17651564
 H                 -0.92596704    0.41912766   -2.35143453

C H N O 0
6-31G(d)
****






