%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                 -0.06177671   -0.93026033   -0.02538156
 C                  1.17305498   -0.25679127   -0.00370663
 C                  1.23641558    1.13740677    0.01719191
 C                  0.06100761    1.89092245    0.01670901
 C                 -1.17626781    1.23644466   -0.00482081
 C                 -1.23774268   -0.15476287   -0.02560981
 H                  2.09328030   -0.83678562   -0.00321492
 H                  2.20331003    1.63322400    0.03377693
 H                  0.10526550    2.97639428    0.03284892
 H                 -2.09652537    1.81464272   -0.00543679
 H                 -2.20814299   -0.64215826   -0.04222324
 H                  0.96346332   -2.72722189   -0.18668790
 N                 -0.06824238   -2.40355517   -0.04680216
 H                 -0.55109987   -2.93096548    0.65225937

C H N 0
6-31G(d)
****






