%nprocshared=24
%mem=41GB
#p opt=(maxstep=10,calcfc) freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq with calcfc and smaller step

0 1
 C                 -1.25750036   -1.10329366   -0.00254534
 C                  0.11402999   -1.83562054    0.22145316
 C                 -2.16869175   -1.16737567    1.14098161
 H                 -3.19309636   -0.83483291    0.99501415
 C                  0.34329597   -2.97209293   -0.75901411
 C                  0.89253070   -2.68115458   -2.01798088
 C                 -0.01224737   -4.29496594   -0.46423347
 C                  1.07444614   -3.69198688   -2.96219967
 H                  1.17837157   -1.65739973   -2.24893075
 C                  0.18355642   -5.31140729   -1.40267077
 H                 -0.44010539   -4.53225864    0.50752924
 C                  0.72281462   -5.01159301   -2.65559004
 H                  1.49763225   -3.45457303   -3.93456368
 H                 -0.09016902   -6.33443237   -1.15696566
 H                  0.86950906   -5.79965358   -3.38858313
 N                 -0.51391201   -2.11767635    2.59026763
 C                 -0.18604121   -2.49004769    3.97554959
 H                 -0.25238655   -1.59617361    4.59922209
 H                 -0.90847780   -3.23296455    4.32281294
 H                  0.82151672   -2.90328922    4.02293338
 C                  0.33576575   -2.27436150    1.62436696
 H                  1.28115689   -2.74477893    1.87211113
 C                 -1.81885363   -1.58518792    2.37507431
 H                 -2.45431553   -1.58418369    3.24850360
 H                 -1.75351962   -1.46496621   -0.90909306
 P                 -0.03202008    3.13959930   -0.71529919
 Au                -0.83504283    0.97904269   -0.35539355
 C                  0.34848018    4.03560937    0.84383963
 H                  0.97244033    3.38945647    1.46677966
 H                  0.86042686    4.98154052    0.63514507
 H                 -0.58342568    4.23761733    1.37962231
 C                 -1.06090885    4.31824841   -1.68198358
 H                 -1.99727199    4.51262460   -1.15088310
 H                 -0.52210394    5.25999873   -1.82925155
 H                 -1.29557504    3.88093661   -2.65648455
 C                  1.56986593    3.10676854   -1.61831171
 H                  1.40291972    2.73405563   -2.63347500
 H                  1.99683641    4.11433184   -1.66860619
 H                  2.24977665    2.42543732   -1.09975936
 H                  0.95082776   -1.11935680    0.08671757
 O                  2.33574518    0.26190368    0.14559797
 C                  2.26194003    0.85719104    1.26317789
 O                  1.25000349    0.93762005    2.01177030
 C                  3.53092896    1.61179162    1.71045028
 H                  3.52680300    1.81053555    2.78657623
 H                  4.43526580    1.05949452    1.43599816
 H                  3.56657441    2.57888838    1.19020644

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



