%nprocshared=24
%mem=41GB
#p opt freq b3lyp gen empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

0 1
 H                  2.19510900   -0.31390700   -1.44020100
 O                  1.25061200   -0.06840300   -1.33851500
 C                 -0.95859800    0.01186700   -0.00036300
 S                  0.89932800    0.07832900    0.24115800
 O                  1.31790900   -1.11564200    0.96618700
 O                  1.24341100    1.40797700    0.72712600
 H                 -1.28913000   -1.10846800   -0.63485700
 H                 -1.35377500    1.06977100   -0.70166300
 H                 -1.51101500    0.03089200    1.20815100

-C -H -N -P -O -S 0
6-31G(d)
****





