%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.26463366   -1.52603620   -3.74645549
 Au                 0.22686646   -0.63061717   -1.62305518
 C                 -1.96657965   -2.20918358   -3.88172119
 H                 -2.69335013   -1.41632485   -3.68231553
 H                 -2.13959476   -2.61828649   -4.88266812
 H                 -2.09974401   -2.99999408   -3.13771933
 C                  0.81625715   -2.92415186   -4.25375633
 H                  0.73860352   -3.72947063   -3.51750292
 H                  0.51836957   -3.30051258   -5.23801605
 H                  1.85572125   -2.58600862   -4.29365332
 C                 -0.14616850   -0.33970097   -5.14601602
 H                  0.87236744    0.05508307   -5.20390876
 H                 -0.39846269   -0.83400680   -6.09013426
 H                 -0.83496261    0.49322957   -4.97720720
 C                  0.61865825    0.13445377    0.26997761
 C                  1.07074722   -0.87176551    1.32185096
 H                  1.96289901   -1.36313609    0.90982826
 C                  0.47515767    1.43850750    0.54986050
 H                  0.66712605    1.86867706    1.53734158
 C                  1.45036197    1.73336138    4.22515535
 H                  0.77916631    2.30949862    4.86354868
 H                  2.27734158    1.33266599    4.82863902
 H                  1.91697174    2.39895420    3.48945855
 C                  1.62658694   -0.24592703    2.65103039
 H                  2.53900268    0.31130406    2.41790445
 H                  1.94869478   -1.08298020    3.28969339
 C                  0.76784224    0.60359391    3.52709552
 C                 -0.57765409    0.31380657    3.81752760
 H                 -1.09974515   -0.32797951    3.11187603
 H                 -1.16748403    1.16338604    4.17058533
 Si                -0.64611885   -0.82347708    5.52300011
 C                  0.74873952   -2.07345579    5.56502855
 C                 -2.32294226   -1.63470367    5.30823635
 C                 -0.54702303    0.40116752    6.94018607
 H                  1.73608967   -1.60855274    5.65542426
 H                  0.60390182   -2.70679810    6.44976733
 H                  0.73675836   -2.72580545    4.68675799
 H                 -2.55700247   -2.22934066    6.19968872
 H                 -3.11581329   -0.89130611    5.17444260
 H                 -2.31843009   -2.30188619    4.43933265
 H                 -1.33411987    1.15999475    6.87539211
 H                 -0.67137372   -0.13573865    7.88868543
 H                  0.42308940    0.90852275    6.97197625
 H                  0.36827076   -1.66029495    1.49403732
 C                  0.02385602    2.46432753   -0.50636868
 C                  0.97275565    3.12529995   -1.28686620
 C                 -1.33351061    2.73258587   -0.68283800
 C                  0.56432770    4.05480170   -2.24312706
 H                  2.04284293    2.91415303   -1.14696626
 C                 -1.74228353    3.66161836   -1.64002828
 H                 -2.08153549    2.21159614   -0.06789288
 C                 -0.79364220    4.32281933   -2.42004746
 H                  1.31223719    4.57628826   -2.85792758
 H                 -2.81259875    3.87262275   -1.77922851
 H                 -1.11543752    5.05569550   -3.17412745

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



