%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

1 1
 P                  0.20272141   -0.68891133   -4.48359463
 Au                 0.18194757    0.29437368   -2.34514134
 C                 -1.45345534   -0.82867703   -5.26660025
 H                 -1.89627303    0.16671162   -5.36393032
 H                 -1.36921169   -1.28858740   -6.25664649
 H                 -2.10311950   -1.44102663   -4.63477441
 C                  0.87034617   -2.40076679   -4.52215493
 H                  0.26091587   -3.04308826   -3.87982438
 H                  0.85789932   -2.79304640   -5.54462511
 H                  1.89703347   -2.40076316   -4.14477618
 C                  1.21289687    0.22443774   -5.71732201
 H                  2.25082097    0.27245203   -5.37518838
 H                  1.17329174   -0.27650687   -6.69026052
 H                  0.82963215    1.24393992   -5.81806542
 C                  0.13001405    1.05261511   -0.40340783
 C                 -0.11436635    0.03323349    0.63785058
 H                  0.21430793   -0.96511205    0.35804326
 C                  0.32953518    2.36331934   -0.16938885
 H                  0.44106702    3.06017230   -0.99708818
 H                  0.41694174    2.81012534    0.82344853
 C                 -1.36563631   -0.00920399    1.42187908
 C                 -2.20966928    1.10514594    1.58208531
 C                 -1.72125364   -1.22218389    2.05043477
 C                 -3.36416624    1.01087487    2.35703715
 H                 -1.97377837    2.03437949    1.07643220
 C                 -2.87857554   -1.31554087    2.81953032
 H                 -1.07879488   -2.09126220    1.93208034
 C                 -3.70145441   -0.19545289    2.97811813
 H                 -4.00953393    1.87763720    2.46576905
 H                 -3.13834046   -2.25733690    3.29322640
 H                 -4.60580514   -0.26515754    3.57544788
 C                  1.12127917    2.31067966    2.64652885
 H                  0.16630575    2.85825260    2.59459751
 H                  1.61826326    2.62827326    3.57169120
 H                  1.71890753    2.58223810    1.77351623
 C                  1.09394513    0.00757675    1.59759012
 H                  1.87127413    0.31163662    0.89671903
 H                  0.98126094   -1.07018925    1.73729083
 C                  0.77992890    0.85333164    2.67864111
 C                  0.04210576    0.36330457    3.84336102
 H                 -0.73253957   -0.36307415    3.55183633
 H                 -0.42080597    1.16779338    4.43064566
 Si                 1.16369326   -0.66020745    5.06148059
 C                  1.46309459   -2.35192578    4.27517937
 C                  0.16808372   -0.80310006    6.65502559
 C                  2.77896621    0.27203744    5.33159125
 H                  2.31988871   -2.33832775    3.59227469
 H                  1.67200624   -3.09555842    5.05491178
 H                  0.58630568   -2.69688151    3.71600584
 H                  0.72372094   -1.39704884    7.39162556
 H                 -0.02665925    0.18223040    7.09309147
 H                 -0.79520819   -1.29706693    6.48286870
 H                  2.59645338    1.30126020    5.66112370
 H                  3.38250688   -0.22217939    6.10360910
 H                  3.37516938    0.30793282    4.41240831

-C -H -P -N -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD




