%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.29249329    1.69902938   -2.81643446
 Au                -0.05212546    0.96516180   -0.60157326
 C                 -1.22123044    1.71759539   -3.86057969
 H                 -1.97143315    2.36740703   -3.40055554
 H                 -0.99103524    2.08401271   -4.86645481
 H                 -1.62979964    0.70506364   -3.92817489
 C                  1.49302806    0.70280826   -3.78898302
 H                  1.14544980   -0.33286386   -3.84424228
 H                  1.59641591    1.10607366   -4.80182916
 H                  2.46659422    0.71884175   -3.29060520
 C                  0.93580412    3.41745674   -2.93388233
 H                  1.89037742    3.48497123   -2.40407248
 H                  1.07873615    3.70629467   -3.98052261
 H                  0.22630270    4.10264759   -2.46105131
 C                 -0.31258773    0.31404694    1.35276015
 C                 -0.40938326   -1.19904743    1.51060033
 H                 -1.11023050   -1.59566802    0.76502277
 C                 -0.34372599    1.11703545    2.43898158
 H                 -0.35761386    0.67124276    3.43946862
 C                  2.18400159   -4.04909447    2.15575661
 H                  2.16146835   -5.13999825    2.16423223
 H                  2.98324475   -3.68276100    1.50268107
 H                  2.43168221   -3.70690813    3.17223058
 C                  0.89158966   -2.01050669    1.38175115
 H                  1.72982673   -1.51165329    1.88288580
 H                  1.19240418   -2.03683204    0.31954352
 C                  0.87225134   -3.44001313    1.80523937
 C                 -0.29596272   -4.22115805    1.81306110
 H                 -1.23861899   -3.68531227    1.92409441
 H                 -0.23757854   -5.13624592    2.40722144
 Si                -0.50875380   -5.04719875   -0.05070657
 C                 -0.88805050   -3.66787622   -1.26224204
 C                 -1.98130739   -6.16748009    0.25790528
 C                  1.06459226   -5.97577130   -0.46860150
 H                 -0.04654502   -2.98297491   -1.40903280
 H                 -1.11127732   -4.12162149   -2.23638177
 H                 -1.76572919   -3.08778506   -0.95832496
 H                 -2.24871672   -6.67561317   -0.67669289
 H                 -1.75341072   -6.93095460    1.00911992
 H                 -2.85090264   -5.59334985    0.59493691
 H                  1.32942365   -6.70340601    0.30631353
 H                  0.90653590   -6.52836601   -1.40308805
 H                  1.91475426   -5.30251532   -0.62202227
 H                 -0.88289289   -1.42449831    2.47470747
 C                 -0.30581673    2.59356686    2.49202525
 C                  0.36033994    3.22179109    3.56136451
 C                 -0.93504637    3.41623925    1.53784689
 C                  0.43940010    4.61198039    3.64913360
 H                  0.83517922    2.60671017    4.32310598
 C                 -0.85768551    4.80713426    1.62350343
 H                 -1.50504430    2.95692132    0.73557654
 C                 -0.16416795    5.41310777    2.67523439
 H                  0.97147536    5.07036027    4.47873800
 H                 -1.35449714    5.41943340    0.87501929
 H                 -0.10773418    6.49601711    2.74359915

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



