%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

1 1
 P                 -0.65426845   -0.18604169   -4.34361853
 Au                 0.31625030    0.01139757   -2.20924920
 C                 -2.03781825    0.97967124   -4.66611733
 H                 -1.67746078    2.00736193   -4.56392554
 H                 -2.43461195    0.83200104   -5.67612368
 H                 -2.83403074    0.81389491   -3.93446397
 C                 -1.36029713   -1.84566134   -4.69580443
 H                 -2.14639445   -2.07015784   -3.96924604
 H                 -1.78023377   -1.87424937   -5.70656681
 H                 -0.57526086   -2.60200894   -4.60754686
 C                  0.52250614    0.11095790   -5.72342940
 H                  1.34333718   -0.60999596   -5.66802671
 H                  0.01289717    0.00887702   -6.68715547
 H                  0.93651000    1.11955964   -5.63645324
 C                  1.04160446    0.40061913   -0.29316254
 C                  0.31599805   -0.32579063    0.76454223
 H                 -0.13859000   -1.25147902    0.41868569
 C                  2.07016561    1.24486584   -0.08985770
 H                  2.51011189    1.80043891   -0.91357705
 H                  2.52421035    1.41882852    0.88246917
 C                 -0.53470540    0.36444033    1.74529803
 C                 -0.34527065    1.70993424    2.11798555
 C                 -1.56582786   -0.36948949    2.36849839
 C                 -1.15426210    2.29311427    3.08881305
 H                  0.41794875    2.30185571    1.62554888
 C                 -2.37407488    0.21606085    3.33873030
 H                 -1.72491200   -1.40639287    2.08766634
 C                 -2.16674329    1.54866670    3.70420110
 H                 -1.00089164    3.33307501    3.36140209
 H                 -3.15794535   -0.36624330    3.81231942
 H                 -2.79605599    2.00937953    4.46002850
 C                  2.81284312    0.36954506    2.73462671
 H                  2.46094343    1.40822951    2.75805709
 H                  3.44029958    0.21700864    3.61800918
 H                  3.41829817    0.26699574    1.83570358
 C                  1.34092002   -1.25867428    1.54672954
 H                  2.08607030   -1.26855209    0.76013073
 H                  0.67882250   -2.11566756    1.56897926
 C                  1.65242749   -0.58361409    2.72132434
 C                  0.80783397   -0.69204048    3.90265577
 C                  0.78491244    0.34212906    4.86719031
 C                 -0.04511084   -1.80388064    4.09896839
 C                 -0.08656563    0.28728274    5.94887048
 H                  1.42085152    1.21093710    4.75448697
 C                 -0.89610155   -1.86707074    5.19386171
 H                 -0.01606969   -2.64028868    3.40820298
 C                 -0.93056430   -0.81493084    6.11544718
 H                 -0.10859815    1.10319890    6.66452253
 H                 -1.53461653   -2.73430154    5.33049638
 H                 -1.60559234   -0.85889691    6.96511099

-C -H -P -N -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



