%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.49443633   -0.28273429   -4.22168630
 Au                 0.27050924    0.35245404   -2.09562487
 C                 -2.29414449   -0.66996710   -4.27208765
 H                 -2.86249679    0.20792181   -3.96427651
 H                 -2.59452937   -0.96599466   -5.28130203
 H                 -2.50449380   -1.48486915   -3.57352771
 C                  0.30510275   -1.78753511   -4.90414646
 H                  0.14878569   -2.62451970   -4.22325734
 H                 -0.11299290   -2.03403304   -5.88574578
 H                  1.38449095   -1.61213805   -5.00366584
 C                 -0.27460729    0.98284166   -5.53711029
 H                  0.78847394    1.21856533   -5.63935922
 H                 -0.66390025    0.61351747   -6.49343858
 H                 -0.81142194    1.89342967   -5.25618522
 C                  0.93322737    0.93739831   -0.18925806
 C                  1.10007015   -0.18015297    0.82664331
 H                  1.89022274   -0.85838244    0.45001511
 C                  1.25394943    2.20813703    0.10622144
 H                  1.14606335    3.00231814   -0.62466321
 H                  1.66255199    2.50859597    1.07433929
 C                 -0.14481722   -1.00197834    1.10239654
 C                 -1.44066005   -0.50002620    0.91088708
 C                  0.00883579   -2.28941863    1.62913748
 C                 -2.55387285   -1.24960132    1.28976302
 H                 -1.57061486    0.49183664    0.48984708
 C                 -1.09979159   -3.04096554    2.01889982
 H                  1.01192230   -2.69971339    1.76171091
 C                 -2.38344378   -2.51419502    1.86278752
 H                 -3.54998679   -0.84208568    1.15507341
 H                 -0.96189105   -4.03375674    2.44372646
 H                 -3.25080210   -3.09038008    2.17480991
 C                  2.58028784   -1.04449081    4.02259000
 C                  3.66614885   -0.73993427    3.30769631
 C                  3.23208085    0.10193790    2.17139748
 N                  1.44790985   -0.39727002    3.44483062
 H                  2.45168203   -1.60373944    4.93980361
 H                  4.69362067   -1.03827244    3.48633328
 N                  1.80232709    0.26522200    2.25100167
 O                  3.90024606    0.54888787    1.26874465
 C                  0.29497102   -0.34214152    4.07883003
 H                  0.24027721   -1.03883232    4.91442773
 C                 -0.83222169    0.49864854    3.85221082
 C                 -0.79070288    1.68228581    3.08168508
 C                 -2.04193026    0.11443821    4.48475743
 C                 -1.93454247    2.44918187    2.93762917
 H                  0.13369863    1.98026748    2.59837993
 C                 -3.19127048    0.87239553    4.30379836
 H                 -2.07220049   -0.79068598    5.08557568
 C                 -3.13448422    2.04073790    3.53372719
 H                 -1.90191817    3.36137992    2.35286459
 H                 -4.11963386    0.56774360    4.76870131
 H                 -4.03132781    2.63662934    3.39795551

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



