%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -1.21483092   -0.25297451   -2.80978569
 Au                -0.48489934    0.22596525   -0.62686400
 C                 -1.25279206    1.19557605   -3.93999687
 H                 -0.25416865    1.63806313   -3.99812589
 H                 -1.57383916    0.88965515   -4.94130430
 H                 -1.94626079    1.94569437   -3.54908130
 C                 -2.90606322   -0.96182991   -2.92811610
 H                 -3.62753461   -0.25607608   -2.50648669
 H                 -3.16306940   -1.16287453   -3.97333408
 H                 -2.95199447   -1.89356665   -2.35712184
 C                 -0.14873212   -1.47357999   -3.67638211
 H                 -0.14156409   -2.41259606   -3.11549254
 H                 -0.52095561   -1.65694224   -4.68964314
 H                  0.87432631   -1.09003237   -3.72803865
 C                  0.19541738    0.58100888    1.31063594
 C                 -0.93532197    0.85209250    2.25110569
 H                 -1.67721171    1.53405081    1.82775756
 C                  1.47274874    0.48284551    1.73641548
 H                  1.70093238    0.56539303    2.80158914
 H                 -0.60075128    1.25807290    3.20850827
 O                 -1.78891614   -0.33284755    2.65919103
 C                 -3.09079556   -0.45841957    2.00330651
 H                 -3.61832125    0.49461410    2.04105328
 H                 -2.89812157   -0.76561287    0.97581354
 H                 -3.63493500   -1.23356484    2.54160638
 H                 -1.83404124   -0.44553368    3.71455347
 O                 -1.87869102   -0.57430515    5.14044632
 C                 -0.75363294    0.03023583    5.83023062
 H                  0.17895839   -0.48539660    5.58255342
 H                 -0.71467811    1.06481539    5.48842491
 H                 -0.93080142    0.00103618    6.90771895
 H                 -1.95910801   -1.50669300    5.40653467
 C                  2.67218462    0.20103603    0.92076706
 C                  3.70677716   -0.56861634    1.48401865
 C                  2.84691214    0.68449192   -0.38919554
 C                  4.84977938   -0.88780795    0.75055647
 H                  3.60221243   -0.93045443    2.50471252
 C                  3.99069180    0.36839695   -1.12368487
 H                  2.09159848    1.33358334   -0.82231198
 C                  4.99413286   -0.42578362   -0.56102081
 H                  5.62957619   -1.49400523    1.20390597
 H                  4.10590955    0.75839380   -2.13176874
 H                  5.88637421   -0.66731668   -1.13192122

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



