%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -1.21980453   -0.45648955   -3.21630678
 Au                -0.55893150    0.25945896   -1.07869468
 C                  0.11698111   -0.31785751   -4.47007697
 H                  0.98119990   -0.90359786   -4.14385608
 H                 -0.22710338   -0.68621553   -5.44211219
 H                  0.42077102    0.72880672   -4.56505550
 C                 -2.63120727    0.46233062   -3.95118072
 H                 -2.37601148    1.52309832   -4.02882603
 H                 -2.86309852    0.07040728   -4.94706902
 H                 -3.50924705    0.35919206   -3.30706673
 C                 -1.73608344   -2.21814692   -3.29605319
 H                 -2.58946677   -2.37871166   -2.63097679
 H                 -2.01723225   -2.48691494   -4.31959977
 H                 -0.91020916   -2.85466751   -2.96567805
 C                  0.06095264    0.83532915    0.82348345
 C                 -1.08701775    1.23176368    1.71297516
 H                 -1.85840637    1.78609365    1.16792827
 C                  1.32964506    0.78174788    1.28721663
 H                  1.55442427    0.98063850    2.34156022
 H                 -2.28017741   -0.54427707    1.68390230
 H                 -2.59719054    0.44849396    2.98288707
 N                 -1.84388753    0.06950996    2.38078560
 N                 -1.05614072   -0.72464542    3.26505365
 H                 -0.11414918   -0.87256878    2.90968729
 C                 -1.19905160   -0.32234555    4.60139546
 O                 -2.13176826    0.37004284    4.96873895
 O                 -0.23000576   -0.84008462    5.33572556
 C                 -0.30591605   -0.56744932    6.75993229
 H                 -1.22794012   -0.98557534    7.16846158
 H                  0.56628364   -1.05871793    7.18668796
 H                 -0.27166851    0.50976611    6.93380980
 H                 -0.76099411    1.84729652    2.55544411
 C                  2.54107198    0.40435713    0.52769846
 C                  2.74434182    0.76900097   -0.81595996
 C                  3.54970522   -0.33219433    1.17470404
 C                  3.89204560    0.36753934   -1.50100328
 H                  2.00847299    1.39175185   -1.31580098
 C                  4.69626279   -0.73653179    0.49033749
 H                  3.42258884   -0.60344566    2.22048017
 C                  4.86929382   -0.39400700   -0.85398085
 H                  4.03000311    0.66428711   -2.53740720
 H                  5.45574654   -1.31692130    1.00717166
 H                  5.76430736   -0.70306896   -1.38660944

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



