%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.06707552   -1.90378479   -3.13531290
 Au                -0.06986833   -0.67058384   -1.13579668
 C                 -1.67846152   -1.91512454   -4.01936628
 H                 -1.96364608   -0.88909811   -4.26922543
 H                 -1.60868318   -2.50797843   -4.93732118
 H                 -2.44490409   -2.34147412   -3.36645081
 C                  0.34227948   -3.68335811   -2.92978609
 H                 -0.37382408   -4.13938550   -2.24112226
 H                  0.30483298   -4.19972402   -3.89468759
 H                  1.34530666   -3.77972195   -2.50399965
 C                  1.13168686   -1.30831776   -4.39473889
 H                  2.14474888   -1.36071249   -3.98547514
 H                  1.07322687   -1.92075480   -5.30058905
 H                  0.90987892   -0.26662660   -4.64461265
 C                 -0.08222975    0.40002283    0.64475888
 C                 -0.19046830   -0.38378404    1.92693069
 H                  0.62710240   -1.09739210    2.08113342
 C                 -0.01859386    1.74438809    0.79903035
 H                 -0.09381706    2.15773996    1.81192205
 H                 -0.94211040    1.13805601    3.15943839
 H                  0.69004934    1.17725912    3.03930438
 C                  0.00573374   -0.11005986    4.49344465
 C                  1.16758242   -0.81545323    4.79619513
 C                 -1.05438499   -0.01070621    5.38950891
 C                  1.26337455   -1.44224598    6.03947932
 H                  1.98533933   -0.87705491    4.08458724
 C                 -0.94398680   -0.63969258    6.63145922
 H                 -1.95443595    0.53695333    5.12778570
 C                  0.21106923   -1.35446616    6.95614093
 H                  2.16486524   -1.99122861    6.29203113
 H                 -1.76161767   -0.56550422    7.34116168
 H                  0.29392164   -1.84012766    7.92347504
 N                 -0.10641883    0.54292002    3.17226532
 C                  0.09976783    2.78459445   -0.24040857
 C                  0.78330128    2.59565474   -1.45668713
 C                 -0.48729725    4.04185772   -0.00194563
 C                  0.83722112    3.60940778   -2.41329420
 H                  1.29392173    1.65511764   -1.63954622
 C                 -0.43956569    5.05457680   -0.96003924
 H                 -0.99948630    4.21802328    0.94142353
 C                  0.21891835    4.84058349   -2.17422417
 H                  1.37616779    3.44232939   -3.34233346
 H                 -0.91203130    6.01188125   -0.75698949
 H                  0.26379068    5.62987061   -2.91948022
 H                 -1.14361416   -0.90525637    2.03259750

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



