%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

1 1
 P                 -0.32941680    0.43417817   -3.64978368
 Au                 0.58404932   -0.13740974   -1.49517422
 C                 -0.56937108    2.23989126   -3.89236107
 H                  0.40007878    2.74440972   -3.85634500
 H                 -1.04546053    2.43593749   -4.85900643
 H                 -1.19904048    2.63375325   -3.08978629
 C                 -2.00689671   -0.27936109   -3.88262571
 H                 -2.65752797    0.04892680   -3.06732445
 H                 -2.43027403    0.04236563   -4.83983791
 H                 -1.94422510   -1.37104011   -3.86197997
 C                  0.60291286   -0.09974104   -5.13983937
 H                  0.72321447   -1.18658977   -5.12475472
 H                  0.06970710    0.19552794   -6.04930535
 H                  1.59399985    0.36229851   -5.13342150
 C                  1.46770461   -0.64984566    0.32879170
 C                  0.52048178   -1.35081417    1.27547454
 H                  0.44337835   -2.39549631    0.95563973
 C                  2.76982089   -0.44832346    0.58478143
 H                  3.42469156    0.00141363   -0.15634033
 H                  3.28241824   -0.71412427    1.51421636
 C                 -0.87391247   -0.77164121    1.38297895
 C                 -1.08532664    0.61540799    1.39621938
 C                 -1.97086306   -1.63252077    1.50496507
 C                 -2.37384711    1.12917711    1.53226262
 H                 -0.23813924    1.28682972    1.29957600
 C                 -3.26361387   -1.11879611    1.63868257
 H                 -1.81630050   -2.70906702    1.49547361
 C                 -3.46595177    0.26274715    1.65333712
 H                 -2.52674333    2.20454367    1.54477728
 H                 -4.10752917   -1.79657852    1.72860761
 H                 -4.46982197    0.66445606    1.75762462
 H                  2.09312644   -1.70178714    2.68706461
 H                  0.67567257   -2.35647424    3.14932307
 C                  0.84006275   -0.38773044    3.68574378
 C                 -0.26338067   -0.47326914    4.53229851
 C                  1.66751068    0.73216897    3.66519895
 C                 -0.54232442    0.59374559    5.38560903
 H                 -0.90904918   -1.34627729    4.51374985
 C                  1.37705986    1.79291101    4.52599175
 H                  2.51056102    0.78984935    2.98790991
 C                  0.27599756    1.72664260    5.38250247
 H                 -1.40034571    0.53775760    6.04771516
 H                  2.01566512    2.67070359    4.52157922
 H                  0.05573056    2.55641074    6.04691668
 N                  1.08874138   -1.50556336    2.75619665

-C -H -P -N -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



