%nprocshared=24
%mem=41GB
#p opt=(calcfc,maxstep=6) freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt calcfc freq

1 1
 P                 -0.08114224   -0.49426643   -2.59978475
 Au                 0.03581962    0.73643781   -0.63353881
 C                 -0.87358031    0.33815419   -4.02327990
 H                 -0.31184970    1.24061429   -4.27876234
 H                 -0.88710988   -0.33916980   -4.88332021
 H                 -1.89774657    0.61735002   -3.76204459
 C                 -1.00472134   -2.05082278   -2.31729144
 H                 -2.04272845   -1.82126647   -2.06190564
 H                 -0.97656306   -2.66892002   -3.22027323
 H                 -0.54089956   -2.58394759   -1.48268480
 C                  1.58320510   -1.00440039   -3.16762814
 H                  2.07357054   -1.57134719   -2.37178900
 H                  1.49514514   -1.62871277   -4.06271028
 H                  2.18131298   -0.11808570   -3.39571872
 C                  0.00383377    0.81838664    1.78855063
 C                 -1.36215076    0.40730778    2.33669780
 H                 -2.13269443    0.22299547    1.58902516
 C                  0.37670587    2.02453280    1.26096039
 H                  1.42855887    2.27851646    1.14802180
 H                 -0.34317224    2.83629182    1.17699828
 N                  0.29547604   -0.68299822    3.57811676
 C                  0.38574159    0.24070374    4.70800638
 H                 -0.25586028   -0.14307294    5.50409074
 H                  1.42220219    0.23210568    5.05222836
 H                  0.09834087    1.27681666    4.47816348
 H                 -1.74003691    1.13420562    3.06083122
 O                 -0.79279694   -1.84412703    2.01937531
 N                 -1.06149482   -0.85868107    3.09054176
 C                  0.91011552   -0.31242553    2.29095906
 H                  1.98252957   -0.13880741    2.29621031
 C                  0.44928456   -1.55525079    1.51763073
 O                  0.96603589   -2.18531245    0.63209141

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



