%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.11611803   -0.24723617   -2.78515967
 Au                -0.10041681    0.44043066   -0.57309069
 C                 -1.43835408   -0.14598313   -3.75355253
 H                 -1.78756077    0.88982158   -3.77879429
 H                 -1.26400466   -0.49776995   -4.77578865
 H                 -2.20420569   -0.76658218   -3.28017698
 C                  0.65841700   -1.99230221   -2.93858432
 H                 -0.07012390   -2.64545172   -2.45024793
 H                  0.74353070   -2.26538437   -3.99541298
 H                  1.62797584   -2.11775475   -2.44873029
 C                  1.34390646    0.72181258   -3.74274236
 H                  2.32295709    0.64381304   -3.26235271
 H                  1.40709242    0.33686145   -4.76571761
 H                  1.04361061    1.77300615   -3.76576926
 C                 -0.22524046    0.84570131    1.57971231
 C                 -1.43490596    0.22791278    2.32761387
 H                 -2.20706027   -0.25520188    1.72485693
 C                 -0.25578025    2.31746762    1.58409205
 H                  0.60373784    2.82113985    1.14946347
 H                 -0.99723670    2.95869968    2.06953844
 N                  0.64455973   -0.23307783    3.44116426
 C                  0.74871764    0.87875804    4.36534992
 H                  0.29150688    0.58136432    5.30906185
 H                  1.80289753    1.11503535    4.50991663
 H                  0.23006391    1.76508451    3.95972956
 C                 -0.62852807   -0.88089953    3.11963709
 H                 -1.15049064   -1.30847991    3.97140920
 C                 -0.12370544   -1.88881391    2.10986481
 O                 -0.58933446   -2.90270080    1.67657101
 O                  1.06060837   -1.34763724    1.63136745
 H                 -1.91746611    0.86845887    3.07372114
 N                  1.08095181    0.02145545    2.19240725

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



