%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.07347948   -0.08387955   -3.37371179
 Au                 0.11056013    0.09349620   -1.02908570
 C                 -1.66426327    0.52820759   -4.06370020
 H                 -1.79363033    1.58222531   -3.80177629
 H                 -1.67616668    0.42026655   -5.15342604
 H                 -2.49201806   -0.04347130   -3.63406371
 C                  0.06624554   -1.79614920   -4.02794685
 H                 -0.72203599   -2.41850755   -3.59472491
 H                 -0.02857297   -1.79666525   -5.11893002
 H                  1.03708679   -2.21504353   -3.74788729
 C                  1.20813213    0.85296181   -4.30054528
 H                  2.19956722    0.48623624   -4.01950921
 H                  1.06755588    0.72983087   -5.37942161
 H                  1.14226759    1.91430265   -4.04418390
 C                  0.28060347    0.27839760    1.02990339
 C                  0.16428797   -1.01078448    1.82302130
 H                  1.07408003   -1.61099146    1.69288771
 C                  0.51704455    1.46458307    1.61505493
 H                  0.62886107    2.37666761    1.03438146
 H                  0.63794201    1.61218609    2.69042125
 N                 -1.21456804   -0.12618210    3.78463629
 C                 -2.54074251   -0.22343923    3.17298333
 H                 -2.87987509   -1.25905268    3.23243158
 H                 -3.22916106    0.43019007    3.70822864
 H                 -2.45888123    0.09057317    2.13006245
 C                 -0.06486042   -0.94394428    3.35350368
 H                 -0.22893002   -1.96671170    3.71688171
 C                  1.05315607   -0.35400352    4.18728733
 O                  2.21301266   -0.57501321    4.25522972
 O                  0.42227963    0.63314288    5.05534211
 H                 -0.64603971   -1.62971433    1.42344141
 N                 -0.85172726    0.68756199    4.72203367

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



