%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.31653107   -0.07310874   -2.88787817
 Au                -0.48943320    0.06113515   -0.68188277
 C                 -0.29506353   -1.51567425   -3.84704384
 H                 -1.38557363   -1.46955928   -3.91782959
 H                  0.13460976   -1.51371030   -4.85422758
 H                 -0.01519251   -2.44034553   -3.33405175
 C                  2.14716160   -0.19803748   -2.98576756
 H                  2.47908873   -1.09528182   -2.45562562
 H                  2.47408794   -0.24974603   -4.02945544
 H                  2.59566804    0.67645581   -2.50585223
 C                 -0.10188564    1.37942179   -3.93159438
 H                  0.30691464    2.28535969   -3.47480381
 H                  0.31294000    1.26009625   -4.93776927
 H                 -1.18914347    1.47929378   -3.99644815
 C                 -1.15021825    0.20035882    1.27764314
 C                 -1.22273774   -1.03420281    2.14223721
 H                 -1.37170530   -1.94677522    1.55890496
 C                 -1.43837249    1.39376361    1.86816007
 H                 -1.39620766    2.32896603    1.31667246
 H                 -1.78270779    1.47856103    2.90247365
 C                  1.63327387    0.20267567    2.03900085
 N                  0.39216728   -0.15340518    3.78975890
 O                  1.22684320   -1.09129900    1.95621585
 O                  2.40715314    0.76154551    1.32654540
 C                 -0.27271657   -0.00386503    5.08218259
 H                  0.06702251   -0.81886810    5.72586327
 H                 -0.00096543    0.96698247    5.49110592
 H                 -1.35317317   -0.08124092    4.93677564
 H                 -1.99480937   -0.99888720    2.92102747
 C                  1.02993078    0.78333604    3.24827612
 H                  1.07182235    1.78445228    3.62365775
 N                  0.16731527   -1.27337043    2.86678940

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



