%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=maxcyc=512

Opt freq

1 1
 C                 -4.50192432    0.00503978   -0.87353665
 C                 -4.05063408   -1.35259919   -0.30440134
 H                 -3.94630922   -2.10531296   -1.08964125
 C                 -4.72905276    0.96490584    0.30750611
 H                 -5.48620771    1.69389924    0.62400951
 N                 -2.81600717   -0.08703187    1.40688325
 C                 -1.82255252   -0.24333335    2.48151745
 H                 -0.82908061   -0.09447533    2.05180781
 H                 -2.00831872    0.49193411    3.26391579
 H                 -1.90060565   -1.25544927    2.88452938
 C                 -2.66887218   -0.97455676    0.21782513
 H                 -1.98070331   -1.77875762    0.46608698
 C                 -2.15233018   -0.07940207   -0.93790971
 O                 -1.00898971    0.11471532   -1.26496004
 O                 -3.22799494    0.47933696   -1.52264782
 C                 -3.87874532    0.90636524    1.43471860
 H                 -3.95598359    1.52792589    2.32353364
 H                 -4.72066110   -1.73816691    0.46862086
 H                 -5.29607785   -0.00670671   -1.59053190
 P                  3.24276340    0.00095057    0.23855891
 Au                 0.93120843    0.04447841   -0.32716200
 C                  4.21513727   -1.23116995   -0.71468065
 H                  4.12110078   -1.01881525   -1.78343966
 H                  5.27072692   -1.18882461   -0.42690484
 H                  3.82607215   -2.23477609   -0.52033628
 C                  3.60704521   -0.38772688    1.99740950
 H                  3.16898954   -1.35548945    2.25970704
 H                  4.68877958   -0.42906908    2.16031136
 H                  3.18492958    0.38786997    2.64398850
 C                  4.08493198    1.60390174   -0.06028575
 H                  3.60008337    2.38392126    0.53366842
 H                  5.14225005    1.53923199    0.21576000
 H                  4.00088697    1.86630541   -1.11865813

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



