%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.01227915   -0.03556259   -3.20827545
 Au                -0.06243279    0.00599767   -0.85777266
 C                 -1.36600483   -0.96561067   -3.99487898
 H                 -2.32015936   -0.50680000   -3.72072606
 H                 -1.25807454   -0.95423995   -5.08506068
 H                 -1.35483887   -1.99876146   -3.63977900
 C                  1.53193177   -0.80713461   -3.89623546
 H                  1.60230878   -1.84319376   -3.55576530
 H                  1.50842557   -0.78369628   -4.99063629
 H                  2.40964537   -0.25893482   -3.53882566
 C                 -0.04876922    1.62705645   -3.98725227
 H                  0.80208500    2.22244529   -3.64014445
 H                 -0.00961187    1.54261891   -5.07839682
 H                 -0.97156398    2.13517909   -3.69348281
 C                 -0.11398626    0.03304774    1.24358328
 C                 -0.06538034   -1.32373930    1.96763344
 H                  0.69357681   -1.98322505    1.53849750
 C                 -1.27998175    0.84694154    1.83655268
 H                 -1.14109798    1.92098572    1.65051080
 H                 -2.22982904    0.58955474    1.35040615
 N                 -0.72685553   -0.12368128    4.00943684
 C                 -0.87025097   -0.28978530    5.46466382
 H                  0.06471653    0.01587493    5.93804970
 H                 -1.69454351    0.32534673    5.82493015
 H                 -1.06284310   -1.34279021    5.67819604
 C                  0.38343348   -0.87037952    3.35275362
 H                  0.75180573   -1.62691336    4.04032768
 C                  1.46207730    0.17833441    2.98082264
 O                  2.41958700    0.51219235    3.63261240
 O                  1.13147015    0.68955993    1.78205783
 C                 -1.47569524    0.65905614    3.30550375
 H                 -2.28013759    1.17812874    3.82099645
 H                 -1.02657326   -1.84692657    1.96677574

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



