%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.20344764    0.09631725   -2.95680601
 Au                -0.40314129   -0.10272399   -0.68164573
 C                  0.68010345    1.79650327   -3.45616016
 H                  1.52976376    2.12844871   -2.85282165
 H                  0.95498876    1.81703827   -4.51577190
 H                 -0.15973760    2.47546064   -3.28460655
 C                 -1.12859757   -0.38623149   -4.12335375
 H                 -1.99966737    0.25671589   -3.96823742
 H                 -0.78129404   -0.28551902   -5.15666381
 H                 -1.41830664   -1.42396508   -3.93626678
 C                  1.64004757   -0.95234613   -3.40852645
 H                  1.39675340   -2.00226490   -3.22227928
 H                  1.89324445   -0.81806715   -4.46501988
 H                  2.49846123   -0.67563274   -2.79000138
 C                 -0.92411733   -0.29364980    1.28178164
 C                 -0.55332109   -1.49682872    2.03621360
 H                 -0.05280534   -2.23315804    1.40134824
 C                 -1.34676967    0.87299356    2.07189078
 H                 -1.59739779    1.74533443    1.46762527
 H                 -2.12887891    0.69662676    2.81750214
 N                  0.21398130    0.15231733    3.86982037
 C                 -0.62118057   -0.06638601    5.04131449
 H                 -0.24881118   -0.93992700    5.57702414
 H                 -0.54748502    0.81236088    5.68666683
 H                 -1.67363461   -0.24006189    4.78379406
 C                  0.70536784   -0.85538545    3.01245153
 H                  1.18490050   -1.70464166    3.49164862
 C                  1.62188859   -0.03773664    2.10782683
 O                  2.56526163   -0.37679092    1.44694927
 O                  1.13747084    1.24512797    2.14190365
 C                 -0.03084856    1.22657584    2.97876678
 H                 -0.16740483    2.19809815    3.44989743
 H                 -1.26140657   -1.99437806    2.66546683

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



