%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.58157434    0.01223037   -4.10079328
 Au                 0.25438354    0.02890998   -1.89782422
 C                 -2.16231750    0.93140253   -4.29568016
 H                 -2.01308074    1.97614854   -4.00790061
 H                 -2.50974217    0.88565512   -5.33317592
 H                 -2.91956361    0.49318503   -3.63902462
 C                 -0.95740460   -1.66183317   -4.76160290
 H                 -1.69078178   -2.15190822   -4.11459296
 H                 -1.35838222   -1.59080740   -5.77812831
 H                 -0.04390007   -2.26333328   -4.77279652
 C                  0.52612000    0.75359156   -5.36712332
 H                  1.47211700    0.20478736   -5.39003858
 H                  0.05852579    0.71311920   -6.35660173
 H                  0.73260838    1.79559396   -5.10577949
 C                  0.94491906    0.05954742    0.06294847
 C                  0.36002268   -0.99198426    0.99861752
 H                  0.56523213   -1.96445717    0.53029275
 C                  1.84894503    0.95817849    0.48089848
 H                  2.27338687    1.70915388   -0.18149581
 H                  2.22563204    1.00308729    1.50710835
 C                  2.39617164    0.11355093    4.15960774
 H                  2.37668457    0.94927895    4.86043775
 H                  2.55144464   -0.82473115    4.71111626
 H                  3.26283406    0.21278931    3.49550212
 C                  1.08866872   -1.13535979    2.38276634
 H                  2.10889385   -1.48808303    2.20364722
 H                  0.58711933   -1.95090222    2.92649481
 C                  1.14658451   -0.00085837    3.35032549
 C                  0.06049684    0.85205953    3.61796795
 H                 -0.70866054    0.91441019    2.85185967
 H                  0.32704477    1.81368572    4.06357050
 Si                -1.00196870    0.07994602    5.19332370
 C                 -1.11026653   -1.78764337    5.09220773
 C                 -2.66054092    0.90596010    4.90559513
 C                 -0.09831937    0.65799238    6.73191745
 H                 -0.14076252   -2.27932390    5.22441501
 H                 -1.76325032   -2.12944925    5.90562279
 H                 -1.55651095   -2.11864027    4.14967402
 H                 -3.33945688    0.65743165    5.73044142
 H                 -2.56472541    1.99576333    4.85728905
 H                 -3.10880538    0.55221096    3.97067961
 H                  0.00767116    1.74786617    6.75381715
 H                 -0.66848144    0.35521287    7.61883467
 H                  0.89812449    0.21026018    6.81048963
 H                 -0.70481531   -0.94221583    1.09104670

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



