%nprocshared=24
%mem=41GB
#p opt=(calcfc,maxstep=6) freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt calcfc freq

1 1
 P                 -0.19120100   -1.37023400   -3.34285400
 Au                 0.11488400    0.40834700   -1.81594800
 C                 -1.51891900   -2.55549400   -2.87634700
 H                 -2.47090500   -2.02107800   -2.80380900
 H                 -1.60604700   -3.35113300   -3.62343100
 H                 -1.29177400   -2.99868200   -1.90271100
 C                  1.28703200   -2.43358800   -3.59730700
 H                  1.59259900   -2.87070000   -2.64233600
 H                  1.06362700   -3.23507700   -4.30922100
 H                  2.11078200   -1.82505400   -3.98192900
 C                 -0.65329000   -0.83896100   -5.04158400
 H                  0.12723100   -0.18735100   -5.44483200
 H                 -0.77664000   -1.70740800   -5.69776900
 H                 -1.59094200   -0.27709100   -5.00311900
 C                  0.41559700    1.95579200   -0.47243400
 C                  0.99850100    1.59241700    0.88213300
 H                  1.31116600    2.47126000    1.46197200
 C                  0.13961000    3.24778200   -0.72435300
 H                 -0.27051200    3.57860600   -1.67652200
 H                  0.32326400    4.03603600    0.01194000
 C                  0.87959500   -1.53009700    1.91225300
 H                  1.63713900   -2.14073600    2.40582900
 H                 -0.08212600   -2.06383200    1.92551800
 H                  1.12176200   -1.40231100    0.84974600
 C                 -0.06944300    0.80575900    1.75001600
 H                 -0.77357700    0.31383200    1.07379200
 H                 -0.60311400    1.52224900    2.37785600
 C                  0.67709900   -0.19604100    2.54061100
 C                  1.18993000    0.11114100    3.81040500
 H                  1.26249200    1.17498200    4.04972100
 H                  2.03429500   -0.48858000    4.15692500
 Si                -0.25294100   -0.43855300    5.16373200
 C                 -1.76950100    0.60429300    4.81909900
 C                  0.62268500    0.00811400    6.76154400
 C                 -0.55888900   -2.27789900    4.98358200
 H                 -2.22476700    0.36482300    3.85186600
 H                 -2.51781700    0.40396600    5.59620600
 H                 -1.54118000    1.67551500    4.84387100
 H                 -0.03121900   -0.23476100    7.60781900
 H                  1.55201400   -0.55924700    6.87824400
 H                  0.85486200    1.07719700    6.80567700
 H                  0.37684000   -2.84690100    5.00111300
 H                 -1.17162200   -2.61240900    5.82980000
 H                 -1.10163900   -2.52492900    4.06562600
 H                  1.88992400    0.96911300    0.74128700

-C -H -N -P -O -Si 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



