%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.23679156   -0.86059036   -3.73637096
 Au                 0.18353558    0.30602065   -1.73183447
 C                 -1.44320303   -0.05112422   -4.86268185
 H                 -1.07306280    0.93894383   -5.14388150
 H                 -1.58849930   -0.65460383   -5.76467715
 H                 -2.40056489    0.06714261   -4.34678631
 C                 -0.91742403   -2.55126781   -3.49191837
 H                 -1.86440205   -2.48731444   -2.94800228
 H                 -1.08492024   -3.04239166   -4.45642194
 H                 -0.21384641   -3.14439985   -2.90055863
 C                  1.25024785   -1.12395006   -4.78431479
 H                  1.99354015   -1.69697630   -4.22259693
 H                  0.98473250   -1.66820139   -5.69669220
 H                  1.68404181   -0.15605406   -5.05148554
 C                  0.54897297    1.33326054    0.03972052
 C                 -0.01461247    0.69910466    1.29176248
 H                  0.66351012   -0.11072311    1.59216658
 C                  1.26972283    2.47107624    0.04156317
 H                  1.72432938    2.85776710   -0.86710162
 H                  1.44603795    3.07883930    0.93250312
 C                 -2.41737870    0.94581716    3.51287271
 H                 -2.68588352    0.68735862    2.47383941
 H                 -2.99714526    0.32944964    4.19559799
 H                 -2.71199113    1.99894763    3.61486740
 C                 -0.17648006    1.59042485    2.61457558
 H                 -0.69546915    2.51392407    2.35189265
 H                  0.82118881    1.85178954    2.96433843
 C                 -0.94380029    0.83078620    3.62098798
 C                 -0.30160030   -0.02608897    4.56504816
 C                 -1.03456835   -0.63819444    5.62279460
 C                  1.09679265   -0.29720662    4.47480080
 C                 -0.40306908   -1.46443767    6.53821765
 H                 -2.09141275   -0.43900750    5.74361106
 C                  1.71339273   -1.14407930    5.37842999
 H                  1.68950668    0.13472696    3.67801647
 C                  0.96768980   -1.72455991    6.41531181
 H                 -0.97226380   -1.90901699    7.34749361
 H                  2.77376163   -1.35384559    5.28730436
 H                  1.45845826   -2.37832292    7.12992380
 H                 -0.97517870    0.21782861    1.08411422

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



