%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.03809261   -0.28044867   -2.99863767
 Au                -0.00669460    0.28198967   -0.71198120
 C                 -1.42594469    0.46813002   -3.94261494
 H                 -1.35493283    1.55842954   -3.89114568
 H                 -1.39216017    0.15007996   -4.98988296
 H                 -2.37658776    0.15761814   -3.49968876
 C                 -0.18752613   -2.08164447   -3.33128201
 H                 -1.11408536   -2.45872564   -2.88883979
 H                 -0.19685300   -2.27041569   -4.40985054
 H                  0.65744077   -2.60756219   -2.87772446
 C                  1.46668687    0.22818041   -3.92259847
 H                  2.34416033   -0.25418472   -3.48230143
 H                  1.38590314   -0.05681415   -4.97669395
 H                  1.58893006    1.31254443   -3.84821151
 C                  0.01724801    0.80064289    1.30068240
 C                 -0.53723976   -0.26359091    2.19329412
 H                 -0.89976280   -1.12791404    1.63155775
 C                  0.49658462    1.96785648    1.76332897
 H                  0.90885907    2.71460787    1.09019352
 H                  0.51312658    2.24180613    2.81924470
 H                 -1.34671466    0.09891988    2.83003798
 O                  0.42425541   -0.88897004    3.18018994
 C                  0.36297141   -2.34539385    3.30716094
 H                 -0.67019613   -2.66142628    3.45128583
 H                  0.78283254   -2.76132010    2.39164899
 H                  0.97969701   -2.60609974    4.16637188
 H                  0.43538445   -0.39687482    4.12447967
 O                  0.46588735    0.21393258    5.41153999
 C                 -0.81699272    0.28387131    6.08670751
 H                 -1.50240485    0.95032736    5.55485286
 H                 -1.20743749   -0.73399868    6.08944547
 H                 -0.66799274    0.62888832    7.11233841
 H                  0.85718893    1.10364865    5.36705106

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



